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[资源] PHYSICAL-CHEMICAL MECHANICS OF DISPERSE SYSTEMS AND MATERIALS

PHYSICAL-CHEMICAL MECHANICS OF DISPERSE SYSTEMS AND MATERIALS
表面界面科学的最新著作。
This book contains information obtained from authentic and highly regarded sources. Reasonable efforts
have been made to publish reliable data and information, but the author and publisher cannot assume
responsibility for the validity of all materials or the consequences of their use. The authors and publishers
have attempted to trace the copyright holders of all material reproduced in this publication and apologize to
copyright holders if permission to publish in this form has not been obtained. If any copyright material has
not been acknowledged please write and let us know so we may rectify in any future reprint.

CRC Press
Taylor & Francis Group
6000 Broken Sound Parkway NW, Suite 300
Boca Raton, FL 33487-2742
2016 by Taylor & Francis Group, LLC
CRC Press is an imprint of Taylor & Francis Group, an Informa business

Contents
Foreword ...........................................................................................................................................ix
Preface ..............................................................................................................................................xi
Authors ........................................................................................................................................... xiii
Introduction ......................................................................................................................................xv
Section ICoagulation Contacts and Structures
Chapter 1 Surface Forces and Contact Interactions.......................................................................3
1.1 Physical-Chemical Phenomena at Interfaces.....................................................3
1.1.1 Three-Phase Contact Line: Wetting...................................................... 8
1.1.2 Capillary Rise Method........................................................................ 12
1.1.3 Sessile Drop Method........................................................................... 12
1.1.4 Spinning Drop Method........................................................................ 13
1.1.5 Molecular Dynamics of Wetting.........................................................24
1.2 Thermodynamic Characteristics of a Contact between Particles....................26
1.3 Contact Interactions between Solid Surfaces of Different Nature
in Various Liquid Media .................................................................................. 33
1.3.1 Methods Used to Measure Contact Forces.......................................... 33
References...................................................................................................................40
Chapter 2 Adsorption of Surfactants and Contact Interactions................................................... 43
2.1 Adsorption Phenomena at Interfaces................................................................ 43
2.2 Mechanisms of Surfactant Behavior at Different Interfaces............................ 55
2.3 Contact Interactions in the Presence of Surfactants: The Role of
Surfactant Adsorption .....................................................................................60
2.3.1 Contacts between Cellulose Fibers: The Evaluation of
Friction Forces and Contact Strength; the Effects of Common
Papermaking Chemicals ....................................................................64
References................................................................................................................... 72
Chapter 3 Coagulation Structures: Rheological Properties of Disperse Systems....................... 75
3.1 Principles of Rheology..................................................................................... 75
3.1.1 Main Rheological Models................................................................... 75
3.1.1.1 Elastic Behavior................................................................... 75
3.1.1.2 Viscous Flow.......................................................................77
3.1.1.3 Plastic Flow (Plasticity)....................................................... 78
3.1.2 Combination of Rheological Models..................................................80
3.2 Rheological Properties of Coagulation Structures...........................................84
3.2.1 Mechanism of Elastic Aftereffect in Structured Dilute
Suspensions of Bentonite....................................................................97
3.2.1.1 Elasticity Modulus............................................................. 100
3.2.1.2 Viscosity of the Elastic Aftereffect................................... 102
3.2.2 The Role of Contact Interactions in the Rheological Behavior
of Fibrous Suspensions...................................................................... 105
References................................................................................................................. 109
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