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PHYSICAL-CHEMICAL MECHANICS OF DISPERSE SYSTEMS AND MATERIALS
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PHYSICAL-CHEMICAL MECHANICS OF DISPERSE SYSTEMS AND MATERIALS 表面界面科学的最新著作。 This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 2016 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business Contents Foreword ...........................................................................................................................................ix Preface ..............................................................................................................................................xi Authors ........................................................................................................................................... xiii Introduction ......................................................................................................................................xv Section ICoagulation Contacts and Structures Chapter 1 Surface Forces and Contact Interactions.......................................................................3 1.1 Physical-Chemical Phenomena at Interfaces.....................................................3 1.1.1 Three-Phase Contact Line: Wetting...................................................... 8 1.1.2 Capillary Rise Method........................................................................ 12 1.1.3 Sessile Drop Method........................................................................... 12 1.1.4 Spinning Drop Method........................................................................ 13 1.1.5 Molecular Dynamics of Wetting.........................................................24 1.2 Thermodynamic Characteristics of a Contact between Particles....................26 1.3 Contact Interactions between Solid Surfaces of Different Nature in Various Liquid Media .................................................................................. 33 1.3.1 Methods Used to Measure Contact Forces.......................................... 33 References...................................................................................................................40 Chapter 2 Adsorption of Surfactants and Contact Interactions................................................... 43 2.1 Adsorption Phenomena at Interfaces................................................................ 43 2.2 Mechanisms of Surfactant Behavior at Different Interfaces............................ 55 2.3 Contact Interactions in the Presence of Surfactants: The Role of Surfactant Adsorption .....................................................................................60 2.3.1 Contacts between Cellulose Fibers: The Evaluation of Friction Forces and Contact Strength; the Effects of Common Papermaking Chemicals ....................................................................64 References................................................................................................................... 72 Chapter 3 Coagulation Structures: Rheological Properties of Disperse Systems....................... 75 3.1 Principles of Rheology..................................................................................... 75 3.1.1 Main Rheological Models................................................................... 75 3.1.1.1 Elastic Behavior................................................................... 75 3.1.1.2 Viscous Flow.......................................................................77 3.1.1.3 Plastic Flow (Plasticity)....................................................... 78 3.1.2 Combination of Rheological Models..................................................80 3.2 Rheological Properties of Coagulation Structures...........................................84 3.2.1 Mechanism of Elastic Aftereffect in Structured Dilute Suspensions of Bentonite....................................................................97 3.2.1.1 Elasticity Modulus............................................................. 100 3.2.1.2 Viscosity of the Elastic Aftereffect................................... 102 3.2.2 The Role of Contact Interactions in the Rheological Behavior of Fibrous Suspensions...................................................................... 105 References................................................................................................................. 109 |
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