| 查看: 5315 | 回复: 74 | |||||||||
| 【奖励】 本帖被评价67次，作者猫鱼是鱼增加金币 52 个 | |||||||||
| 当前只显示满足指定条件的回帖，点击这里查看本话题的所有回帖 | |||||||||
[资源]
纳米大牛夏幼南JACS新作——10 nm银立方的合成以及非均相成核机理
|
|||||||||
|
纳米大牛夏幼南的新作(刚在线发表)，文章介绍了纳米银立方的非均相成核机理以及 SH−在调控纳米银立方生长的作用。。。洋洋洒洒引用49篇文献 标题：Toward the Synthesis of 10-nm Ag Nanocubes with Sharp Corners and Edges: The Roles of Heterogeneous Nucleation and Surface Capping 作者：Aleksey Ruditskiy and Younan Xia 期刊：J. Am. Chem. Soc., (IF=12.113) Just Accepted Manuscript DOI: 10.1021/jacs.5b13163 文章链接：http://pubs.acs.org/doi/abs/10.1021/jacs.5b13163 Publication Date (Web): February 15, 2016 We report a polyol method for the facile synthesis of Ag nanocubes having sharp corners and edges, together with edge lengths below 15 nm. The rapid nucleation of Ag atoms was facilitated through the addition of a trace amount of SH− to generate Ag2S clusters while the corners and edges of the nanocubes were sharpened through the introduction of Br− as a regulator of the growth kinetics and a capping agent for the Ag(100) surface. Because of their much smaller size relative to the more commonly used capping agent based on poly(vinyl pyrrolidone), Br− ions are more effective in passivating the {100} facets on very small Ag nanocubes. The mechanistic roles of these additives, along with the effects of their interactions with other species present in the reaction solution, were all systematically investigated. The concentration of SH− was found to be a particularly effective parameter for tuning the edge length of the nanocubes. As a result of the understanding gained during the course of this study, Ag nanocubes with uniform edge lengths controllable in the range of 13-23 nm could be reliably produced. The nanocubes of 13.4±0.4 nm in edge length constitute the smallest nanocrystals of this kind reported to date; they also possess sharper corners and edges relative to the limited examples of sub-20 nm Ag nanocubes reported in the literature. The availability of such small and sharp Ag nanocubes will open the door to an array of applications in plasmonics, catalysis, and biomedicine.  Schematic illustration showing the formation of Ag nanocubes through heterogeneous nucleation.png [ Last edited by yuan0806 on 2016-2-24 at 13:04 ] |
回复此楼» 本帖附件资源列表
-
欢迎监督和反馈：小木虫仅提供交流平台，不对该内容负责。
本内容由用户自主发布，如果其内容涉及到知识产权问题，其责任在于用户本人，如对版权有异议，请联系邮箱：xiaomuchong@tal.com - 附件 1 : ruditskiy2016.pdf
2016-02-22 09:28:38, 3.95 M
» 收录本帖的淘帖专辑推荐
 uicorn3 | JACS专题 | 材料物理与化学 | 纳米大牛 |
| 纳米材料 | 花未眠 | 文献zy |
» 猜你喜欢
北京航空航天大学26级博士招生-生物医学工程-合成生物学
已经有20人回复
-
温州大学王娟课题组2026年招生
已经有10人回复
-
金属材料论文润色/翻译怎么收费?
已经有166人回复
-
温州大学2026年招生（化学、材料）
已经有10人回复
-
招生负责_院士团队_学生高自由度成长_擅长学生培养
已经有5人回复
-
温州大学招收2026年入学博士研究生（化学、材料、环境）
已经有10人回复
-
非晶合金
已经有2人回复
-
院士团队-每届学生都优秀-高自由度-团队氛围好
已经有0人回复
-
求调剂
已经有1人回复
» 本主题相关商家推荐: (我也要在这里推广)
29楼2016-02-24 13:05:16
简单回复
2016-02-22 09:51
回复
五星好评 顶一下，感谢分享！
马踏冰河3楼
2016-02-22 10:20
回复
五星好评 顶一下，感谢分享！
lwg34楼
2016-02-22 10:58
回复
五星好评 顶一下，感谢分享！
tjuxt5楼
2016-02-23 08:57
回复
五星好评 顶一下，感谢分享！
zjjxl7楼
2016-02-23 09:22
回复
五星好评 顶一下，感谢分享！
2016-02-23 10:24
回复
五星好评 顶一下，感谢分享！
羊驼尊者10楼
2016-02-23 11:08
回复
五星好评 顶一下，感谢分享！
长临河11楼
2016-02-23 11:13
回复
五星好评 顶一下，感谢分享！
hsj12楼
2016-02-23 11:32
回复
五星好评 顶一下，感谢分享！
walkerby14楼
2016-02-23 12:46
回复
五星好评 顶一下，感谢分享！
