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| In fact, as shown in Table 3, although the rate constant (k2) of the cis-to-trans isomerization reaction was higher than that of tetralin hydrogenation reaction (k1) the cis–trans isomerization on Pt and Ni catalysts was taken place when the concentration of tetralin on the surface was decreased . As discussed in previous study, the high adsorption constant of tetralin compared to that of decalin may be ascribed to the parallel adsorption of a more rigid aromatic-containing molecule than a bent naphthenic molecule |
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