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Çë°ïæ·ÒëÒ»ÏÂÏÂÃæ¼¸¾äÓ¢ÎÄ 1.The reactions occur with high selectivity at primary C−H bonds ¦Ã to the hydrosilyl group to form primary alkyl bisboronate esters. 2.These reactions occur with high site selectivity ¦Ã to silicon and with high diastereoselectivity in cases of reactions at secondary C−H bonds. 3.Sawamura et al. have reported the Rh- and Ir-catalyzed borylation of alkyl C−H bonds ¦Á to the nitrogen of amides or ¦Ã to a pyridyl nitrogen. |
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