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¸ß·Ö×ÓרҵӢÓï¸ßÊÖÇë°ïÎÒÐÞ¸ÄÏÂÏÂÃæµÄÎå¾ä»°,ʹ֮Òâ˼¸ü¼ÓÃ÷È·£¬¸üÓÐÎIJɣº ±ÉÈËÔÙ´ÎÏÈл¹ýÁË£¡ °ÑÖÐÎÄÒ²¸½ÉÏÁË! 1.It has been reported that reaction under mild thermal conditions of 110 ¡æ even with the exsistence of little stannous octoate as catalyst can avoid side reaction. ¾Ý±¨µÀ£¬ÔÚ110¡æµÄκ͵ÄÈÈ·´Ó¦Ìõ¼þÏ£¨¼´µÍΣ©£¬ÉõÖÁÔÚÉÙÁ¿µÄ´ß»¯¼ÁµÄ´æÔÚÏ£¬¸±·´Ó¦Ò²¿ÉÒÔ±ÜÃâ¡£ 2.This paper aims at preparing biodegradable aliphatic block copolymers with combined mechanical and thermal properties with reduced cost. ±¾ÎÄÖ¼ÔÚÖÆ±¸µÍ³É±¾ÇÒÁ¦Ñ§ÐÔÄܺÍÈÈÐÔÄܾã¼ÑµÄ¿ÉÉúÎï½µ½âÖ¬·¾×åǶ¶Î¹²¾ÛÎï¡£ 3. Moreover, Tm of chain-extended 2000 based on 20 in Table 3 is lower than that of PBS20, i.e. 108.0 0C in Table 1. The reason is that B group disturbed the crystallite structure and reduced crystallinte size. ÁíÍ⣬Table 3ÖеÄ20»ù£¨ÔÁϵıàºÅ£©µÄǶ¶Î¹²¾ÛÎï2000£¨ÑùÆ·µÄ±àºÅ£©µÄÈÛµã±È20µÄ108.0 0CÒªµÍ¡£ÔÒòÊǸö»ùÍÅBÆÆ»µÁ˾§Ìå½á¹¹Ê¹Çò¾§µÄ³ß´ç±äС¡£ 4.Especially for the tensile strength, the block samples with the same portion of soft block showed the values of 27.8 and 29.8 MPa for 1 and 1¡¯, respectively, in contrast with 18.0 MPa for the random copolymers. ÌØ±ðÊÇÀÉìÇ¿¶È£¬Èí¶Îº¬Á¿ÏàͬµÄǶ¶Î¹²¾ÛÎï1ºÍ1¡¯·Ö±ðΪ27.8 ºÍ29.8 MPa£¬¶ø¶ÔÕÕµÄÎ޹湲¾ÛÎïµÄÀÉìÇ¿¶È½öΪ18.0 MPa¡£ 5.The total effect is the increase of tensile strength because crystallization plays a dominant role in the mechanical property as the relative low concentration of A groups employed in our experiment. ×ܵĽá¹ûÊÇÀÉìÇ¿¶ÈÔö¼ÓÁË£¬ÕâÊÇÒòΪ½á¾§ÔÚÁ¦Ñ§ÐÔÄÜÉÏÆðÁËÖ÷µ¼×÷Óã¬Õâ¿ÉÄÜÊÇÒòΪA»ùÍŵÄŨ¶È½ÏµÍ°É¡£ 6.What should be noteworthy was that block copolymers demonstrated extraordinary toughness with impact strength above 743 J/m (some of the specimens were even not broken when doing the izod impact experiment) for 2010, representing a remarkable 19 times of 38.9 J/m for pure sample. ÖµµÃ×¢ÒâµÄÊÇǶ¶Î¹²¾ÛÎïµÄÈÍÐÔ³¬ºõѰ³££¬Æä³å»÷Ç¿¶È¸ßÓÚ743 J/m£¬ÕâÊÇ´¿ÑùÆ·µÄ38.9µÄ19±¶¡£ÉõÖÁһЩÑùÆ·×öȱ¿Ú³å»÷ʵÑéÊ±ÖØ²»¶Ï¡£ 7. The satisfactory tensile strength of block copolymers may be attributed to the formation of allophanate crosslinks by the introduction of excess TDI. The presence of allophanate crosslinks can be proved by the highest molecular weight of 20 series copolymers, followed by 40 ( in Table 2). This is because polyols with lower molecular weight needs more TDI to chain-extension. As the molar ratio of TDI to polyols was fixed at 2.1/1, relative more excess TDI was applied for 20 based copolymers which would cause more allophanate crosslinks. As a result, highest molecular weight in Table 2 is observed for the 20 based copolymers. The resulted additional chemical tie points by allophanate crosslinks lead to a more uniform stress distribution throughout the sample, thus preventing plastic flow of the crystals and leading to stress-transmission through soft segment. The more uniform stress distribution in combination with increasing chemical crosslinks led to the increasing tensile strength. Ƕ¶Î¹²¾ÛÎïÁîÈËÂúÒâµÄÀÉìÇ¿¶È¹éÓÚ¹ýÁ¿µÄTDIËùÐγɵÄëå»ù¼×Ëáõ¥½»Áª¼ü¡£ëå»ù¼×Ëáõ¥½»Áª¼ü¿ÉÒÔ´Ó20ϵÁеĹ²¾ÛÎïµÄ·Ö×ÓÁ¿×î¸ß£¬Æä´ÎÊÇ40ϵÁеķÖ×ÓÁ¿¶øµÃµ½Ö¤Êµ¡£ÕâÊÇÒòΪµÍ·Ö×ÓÁ¿µÄ¶þ´¼ÐèÒª¸ü¶àµÄTDIÀ´À©Á´¡£ÓÉÓÚTDIÓë¶þ´¼µÄĦ¶û±È¹Ì¶¨Îª2.1/1, ¶Ô20ϵÁÐÀ´½²£¬¹ýÁ¿µÄTDI¾Í»á¶àЩ£¬Õ⽫µ¼ÖÂÐγɸü¶àµÄëå»ù¼×Ëáõ¥½»Áª¼ü¡£Òò´Ë£¬Èç±í2Ëùʾ£¬20ϵÁеķÖ×ÓÁ¿×î¸ß¡£ÑÕÉ«±ê¼ÇµÄ»°Ã»ÓдíÎó£¬Ö»Ðè¸ÄдÏ£¬ÏëÔÚ±£ÁôÔÒâµÄǰÌáÏ»»ÖÖ±í´ï·½Ê½¡£ [ Last edited by wellok101 on 2008-10-5 at 18:33 ] |
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djxustc
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1.It has been reported that side reaction can be avoided with little stannous octoate as catalyst at 110 ¡æ. 2.This paper reports the mechanical and thermal properties of biodegradable multiblock copolymers. 3.Moreover, the Tm of chain-extended 2000 is lower than that of pure sample in Table 3. The reason is that the Diisocyanate reduced crystallinte size and inferior. 4.Especially for the tensile strength, the multiblock samples with the same soft block have the values of 27.8 and 29.8 MPa for 2020 and 4020, respectively, in contrast with 18.0 MPa for the random copolymers. µÚÎå¾ä»°¿´²»³öÄãÒª±í´ïµÄÒâ˼¡£ |
3Â¥2008-10-04 01:52:33
wonderful_me
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Õ⼸¾äÓ¢ÎÄȷʵºÜÖÐÎÄ¡£Õë¶ÔÕ⼸¾ä¸øÂ¥Ö÷Á½¸ö½¨Ò飺 1¡¢Ñ§»áÓñ»¶¯Óï̬£» 2¡¢ÓÐʱÖÐÎĵÄÒ»¾ä»°ÒªÑ§»á²ð·Ö³ÉΪӢÎĵ仰£¬Óüòµ¥¾ä»òÐÞÊξä½Ô¿É¡£ ÒÔµÚÒ»¾äΪÀý£º(ÀÏʵ˵£¬Õâ¾äÕæµÄ²»´ó¿´µÃ¶®,ÊÂʵÉÏÿһ¾ä¶¼¿´²»È«¶®£¬lz×îºÃ¸ø³öÖÐÎÄ) Ծ䣺 It has been reported that reaction under mild thermal conditions of 110 ¡æ even with the exsistence of little stannous octoate as catalyst can avoid side reaction. ¸Äºó£º It has been reported that the side reaction can be avoided (to some extent or effectively??) because XXX reaction is dominant under mild thermal conditions of 110 ¡æ even (in the case of??) using very small amounts of (²»ÒªÓÃlittle) stannous octoate as the catalyst. ÁíÍ⣬²»ÔÞ³ÉlzÃ÷Âë±ê¼Û¡°Ò»¾ä2½ð±Ò£¡¡±£¬Í¨¹ý³æ×Ó¸øÄãµÄ½¨Òé×Ô¼ºÐ޸ģ¬Ìá¸ß²Å¿ì¡£ [ Last edited by wonderful_me on 2008-10-4 at 11:41 ] |

2Â¥2008-10-04 01:26:31
yuepeiiccas
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4Â¥2008-10-04 15:32:14














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