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hanyang1993金虫 (正式写手)
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[求助]
求大神翻译一段摘要
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| Substrate-directed ortho C−H amination of azoarenes using TMSN3 as the source of nitrogen leading to the synthesis of 2-aryl-2H-benzotriazoles has been accomplished with the help of Pd/TBHP combinations. An intermolecular o-azidation (C−N bond formation) followed by an intramolecular N−N bond formation via nucleophilic attack of one of the azo nitrogen onto the o-azide nitrogen leads to cyclization with the expulsion of N2. |
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