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17863813667

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ABSTRACT:We report the synthesis of novel azulenesubstituted methacrylate polymers by free radical polymerization,
in which the azulene moieties represent hydrophobic dipoles
strung pendant to the polymer backbone and impart unique
electronic properties to the polymers. Tunable optoelectronic
properties were realized by adjusting the azulene density, ranging
from homopolymers (having one azulene group per repeat unit) to
copolymers in which the azulene density was diluted with other
pendant groups. Treating these polymers with organic acids
revealed optical and excitonic behavior that depended critically on
the azulene density along the polymer chain. Copolymers of
azulene with zwitterionic methacrylates proved useful as cathode
modification layers in bulk-heterojunction solar cells, where the relative azulene content affected the device metrics and the
power conversion efficiency reached 7.9%
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17863813667

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2楼2015-12-10 23:19:11
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