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zzox

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注册: 2015-11-27
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专业: 化工系统工程

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SciFinder® Page 1

1. Single Step

100%

Overview

Steps/Stages Notes

1.1C:1610424-72-0 reaction products with reduced graphene ox, S

hMe, 12 h, 80°C

solid-supported catalyst, recyclable catalyst, catalyst prepared and used, Reactants: 1, Catalysts: 1, Solvents: 1, Steps: 1, Stages: 1, Most stages in any one step: 1

References

Carbon-based material-supported products and their production and catalysts comprising them

By Mata Martinez, Jose Antonio et al

From PCT Int. Appl., 2015071521, 21 May 2015

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

2. Single Step

100%

Overview

Steps/Stages

1.1R:Me2SiHPh, C:663151-80-2, S:Me2CO, S:MeCN, 1 h, rt

Notes

conversion, 100%, Reactants: 1, Reagents: 1, Catalysts: 1, Solvents: 2, Steps: 1, Stages: 1, Most stages in any one step: 1

References

Process for the catalytic reduction of acid chlorides and imidoyl chlorides to aldehydes and imidoyls

By Nikonov, Georgii et al

From U.S. Pat. Appl. Publ., 20140228579, 14 Aug 2014

SciFinder® Page 2

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

3. Single Step

100%

Overview

Steps/Stages

1.1R:beta-Cyclodextrin, R:NaOCl, S:H2O, 120 min, 10-70°C

Notes

Reactants: 1, Reagents: 2, Solvents: 1, Steps: 1, Stages: 1, Most stages in any one step: 1

References

Method for benzaldehyde preparation through oxidation and real-time monitoring via b-cylcodextrin catalyst

By Shi, Dongpo et al

From Faming Zhuanli Shenqing, 103044219, 17 Apr 2013

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

4. Single Step

100%

Overview

Steps/Stages
1.1C:Me4-piperidoxyl, C:KBr, S:CH2Cl2, S:H2O, 20°C, pH 8

Notes

buffered solution (phosphate), optimization study, Reactants: 1, Catalysts: 2, Solvents: 2, Steps: 1, Stages: 1, Most stages in any one step: 1

References

Fast catalyzed hypohalous oxidation of alcohol groups

By Horn, Clemens Rudolf

From PCT Int. Appl., 2013109670, 25 Jul 2013

Experimental Procedure

SciFinder® Page 3

The micro-reactor used is identical to the one of example IB.Benzyl alcohol (c = I moFl) and 0.2 % (molar) of TEMPO are dissolved in dichloromethane, thus constituting a solution for a first feed (feed 1 = the organic solution (A-T) shown on FIG. 2B).A second feed (feed 2) (B in the figure) is stock solution of bleach (c=11.2 %) at a pH about 12.5. A third feed (feed 3) (BF in the figure) is a 0.7 M phosphate buffer (pH 8), which is brought to pH 6.2 by slow and controlled addition of H3PO4 85 % wt. Feeds 2 and 3 (in a ratio bufbleach of 1.1) are mixed in one fluidic module (the first one Ml of the used microreactor) before passing a control sensor S of set point pH (= 8) and the mixture is then injected in the second module M2 of the micro-reactor. Feed I is directly pumped to the module M2 where it is mixed with aqueous phase.The total ratio (aqueous/organic phase) is 1.33.The temperature is 20°C.The results obtained (conversion (%) and yield (%)) are indicated in the Table 6 below related to different experiments carried out at different residence time (Rt(s)). Yield 100%.

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

5. Single Step

96%

Overview

Steps/Stages

1.1R:H3PO4, S:H2O, S

hMe, 18 h, 25°C

Notes

photochemical, xenon lamp,Ru/SrTiO3:Rh catalyst used, sealed flask used, 420nm used, Reactants: 1, Reagents: 1, Solvents: 2, Steps: 1, Stages: 1, Most stages in any one step: 1

References

Preparation of aldehydes or ketones by photochemical dehydrogenation of primary or secondary alcohols using rhodium-doped strontium titanium oxide having ruthenium supported thereon

By Noyori, Ryoji et al

From Jpn. Kokai Tokkyo Koho, 2014037396, 27 Feb 2014

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

6. Single Step

98%

Overview

Steps/Stages Notes

SciFinder® Page 4
1.1 R:O2, C:CuO, C:Fe2O3, S:MeCN, 6 h, 80°C HZSM-5 zeolite, HZSM-22 zeolite and Y
zeolite used as catalysts, Reactants: 1,
Reagents: 1, Catalysts: 2, Solvents: 1, Steps:
1, Stages: 1, Most stages in any one step: 1
References
Catalyst for oxidation of benzyl alcohol to
benzaldehyde and its preparation method
By Zhang, Lei et al
From Faming Zhuanli Shenqing, 103191769,
10 Jul 2013

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

7. Single Step

99%

Overview

Steps/Stages

1.1R:O2, C:CuO, C:Fe2O3, C:SiO2, C:Al2O3, S:MeCN, 6 h, 80°C

Notes

Reactants: 1, Reagents: 1, Catalysts: 4, Solvents: 1, Steps: 1, Stages: 1, Most stages in any one step: 1

References

Catalyst for oxidation of benzyl alcohol to benzaldehyde and its preparation method

By Zhang, Lei et al

From Faming Zhuanli Shenqing, 103191769, 10 Jul 2013

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

8. Single Step

99%

Overview

Steps/Stages Notes

SciFinder® Page 5
1.1 R:O2, C:CuO, C:Fe2O3, S:MeCN, 6 h, 80°C 4A zeolite used as catalyst, Reactants: 1,
Reagents: 1, Catalysts: 2, Solvents: 1, Steps:
1, Stages: 1, Most stages in any one step: 1
References
Catalyst for oxidation of benzyl alcohol to
benzaldehyde and its preparation method
By Zhang, Lei et al
From Faming Zhuanli Shenqing, 103191769,
10 Jul 2013

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

9. Single Step

98%

Overview

Steps/Stages

1.1R:O2, C:CuO, C:Fe2O3, S:MeCN, 6 h, 80°C

Notes

SAPO zeolite used as catalyst, Reactants: 1, Reagents: 1, Catalysts: 2, Solvents: 1, Steps: 1, Stages: 1, Most stages in any one step: 1

References

Catalyst for oxidation of benzyl alcohol to benzaldehyde and its preparation method

By Zhang, Lei et al

From Faming Zhuanli Shenqing, 103191769, 10 Jul 2013

CASREACT ®: Copyright © 2015 American Chemical Society. All Rights Reserved. CASREACT contains reactions from CAS and from: ZIC/VINITI database (1974-1999) provided by InfoChem; INPI data prior to 1986; Biotransformations database compiled under the direction of Professor Dr. Klaus Kieslich; organic reactions, portions copyright 1996-2006 John Wiley & Sons, Ltd., John Wiley and Sons, Inc., Organic Reactions Inc., and Organic Syntheses Inc. Reproduced under license. All Rights Reserved.

10. Single Step

98%

Overview

Steps/Stages Notes

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