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[资源] wiley上一本书Mesoporous Zeolites: Preparation, Characterization and Applications

介孔分子筛的制备、表征以及应用。
1 Strategies to Improve the Accessibility to the Intracrystalline Void of
ZeoliteMaterials: Some Chemical Reflections 1
Joaquén Pérez-Pariente and Teresa álvaro-Mu˜noz
1.1 Introduction 1
1.2 Strategies to Obtain New Large-Pore Materials 5
1.3 Methodologies to Control the Crystallization Process of Zeolite
Materials in the Absence of Pore-Forming Agents 9
1.3.1 Confined Nucleation and Growth 11
1.3.2 Use of Blocking Agents for Crystal Growth 13
1.3.2.1 Silanization Methods 13
1.3.2.2 Use of Surfactants in the Synthesis of Silicoaluminophosphates 16
1.3.3 Synthesis in the Presence of Pore-Forming Agents 18
1.4 Postsynthesis Methodologies 21
1.4.1 Materials with High Structural Anisotropy: Layered Zeolites 21
1.4.2 Removal/Reorganization of T Atoms in the Crystal Bulk 23
1.5 Conclusions 24
Acknowledgments 25
References 25
2 Zeolite Structures of Nanometer Morphology: Small Dimensions, New
Possibilities 31
Heloise de Oliveira Pastore and Dilson Cardoso
2.1 The Structures of Zeolites 34
2.1.1 FAU and EMT Structures: Zeolites X and Y 34
2.1.2 LTA Structure 50
2.1.3 BEA Structure 52
2.1.4 Pentasil Zeolites, MFI, and MEL Structures: ZSM-5, ZSM-11, and
2.2 The Structures of Zeotypes: Aluminophosphates and
Silicoaluminophosphates 63
2.3 Lamellar Zeolites 66
2.4 Conclusions and Perspectives 71
References 75
3 Nanozeolites and Nanoporous Zeolitic Composites: Synthesis and
Applications 79
Gia-Thanh Vuong and Trong-On Do
3.1 Introduction 79
3.2 Synthesis of Nanozeolites 81
3.2.1 Principles 81
3.2.2 Synthesis from Clear Solutions 87
3.2.2.1 Parameters Affecting the Crystal Size 87
3.2.3 Synthesis Using Growth Inhibitor 90
3.2.4 Confined Space Synthesis 91
3.2.5 Synthesis of Nanozeolites Using Organic Media 95
3.3 Nanozeolite Composites 98
3.4 Recent Advances in Application of Nanozeolites 106
3.5 Conclusions and Perspectives 109
References 110
4 Mesostructured and Mesoporous Aluminosilicates with Improved
Stability and Catalytic Activities 115
Yu Liu
4.1 Introduction 115
4.2 Zeolite/Mesoporous Composite Aluminosilicates 116
4.2.1 Synthesis of Zeolite/Mesoporous Composite Material 116
4.2.2 Catalytic Evaluation of Zeolite/Mesoporous Composite
Material 124
4.3 Posttreatment of Mesostructured Materials 128
4.3.1 Posttreatment of Mesoporous Materials by Zeolite
Structure-Directing Agents or Zeolite Nanocrystals 128
4.3.2 Postsynthesis Grafting of Aluminum Salts on theWalls of
Mesostructured Materials 133
4.4 Mesostructured and Mesoporous Aluminosilicates Assembled from
Digested Zeolite Crystals 135
4.5 Mesostructured and Mesoporous Aluminosilicates Assembled from
Zeolite Seeds/Nanoclusters 141
4.5.1 Assembly of Mesostructured Aluminosilicates from Zeolite Y
Seeds 141
4.5.2 Assembly of Mesostructured Aluminosilicates from Pentasil Zeolite
Seeds 145
4.6 Conclusions 152
References 153
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