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北京石油化工学院2026年研究生招生接收调剂公告
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lewz66

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The influence of platinum (phase) oxide on the electrode kinetics of the manganese(III)/manganese(II) and cerium(IV)/cerium(III) redox couples in sulphuric acid
谢谢!由于急用,在学校下载不了。请帮帮忙。
lwzcjdx2010@yahoo.com.cn
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zhlhuang

金虫 (小有名气)

Title: INFLUENCE OF PLATINUM (PHASE) OXIDE ON THE ELECTRODE KINETICS OF THE MANGANESE(III)/MANGANESE(II) AND CERIUM(IV)/CERIUM(III) REDOX COUPLES IN SULPHURIC ACID.
Source: Electrochimica Acta [0013-4686] Randle yr:1986 vol:31 iss:7 pg:739 -744  

这篇文献比较老,俺们学校没有电子版的全文。
2楼2008-09-12 00:40:48
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zhlhuang

金虫 (小有名气)

下面是这篇文章的一些细节,希望有帮助。
Accession number:  86110169343

Title:  INFLUENCE OF PLATINUM (PHASE) OXIDE ON THE ELECTRODE KINETICS OF THE MANGANESE(III)/MANGANESE(II) AND CERIUM(IV)/CERIUM(III) REDOX COUPLES IN SULPHURIC ACID.

Authors:  Randle, T. H.; Kuhn, A. T.  

Author affiliation:  Swinburne Inst of Technology, Hawthorn, Aust

Serial title:  Electrochimica Acta

Abbreviated serial title:  Electrochim Acta

Volume:  v 31

Issue:  n 7

Issue date:  Jul

Publication year:  1986

Pages:  p 739-744

Language:  English

ISSN:  0013-4686

CODEN:  ELCAAV

Document type:  Journal article (JA)

Abstract:  The kinetics of the Ce(III) Ce(IV) and Mn(II)/Mn(III) redox reactions (both oxidation and reduction) were followed at a rotating Pt disc electrode, on which known amounts of platinum oxide (type II) had been formed. Oxide film inhibits both anodic and cathodic reactions, but to different extents. There is no systematic decrease in i//0 with increase in film thickness suggesting that electron tunnelling is unimportant under these conditions but that electron exchange takes place with the oxide itself. The inhibiting effect of type II oxide is seen even when it is present in sub-monolayer amounts, and this and other effects suggest that the overall behavior of the system cannot be simply represented, for example in terms of a semi-conducting oxide.

Abstract type:  (Author abstract)

Number of references:  35

Ei main heading:  CHEMICAL REACTIONS -- Redox

Ei controlled terms:  ELECTRODES - Platinum  -  PLATINUM COMPOUNDS  -  ELECTROCHEMISTRY - Measurements  -  CERIUM AND ALLOYS  -  MANGANESE AND ALLOYS

Uncontrolled terms:  PLATINUM (PHASE) OXIDE  -  PLATINUM OXIDE  -  ELECTRON TUNNELLING

Ei classification codes:  802 Chemical Apparatus and Plants; Unit Operations; Unit Processes  -  704 Electric Components and Equipment  -  547 Minor, Precious and Rare Earth Metals and Alloys  -  804 Chemical Products Generally  -  801 Chemistry  -  543 Chromium, Manganese, Molybdenum, Tantalum, Tungsten, Vanadium and Alloys

Treatment:  Experimental (EXP)

Database:  Compendex

   Compilation and indexing terms, © 2008 Elsevier Inc.
3楼2008-09-12 00:42:04
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lewz68

铜虫 (小有名气)

非常谢谢!呵呵
4楼2008-09-12 20:46:20
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