| 查看: 5907 | 回复: 48 | |||
| 【奖励】 本帖被评价34次，作者zhanghd增加金币 31.25 个 | |||
| 当前主题已经存档。 | |||
| 当前只显示满足指定条件的回帖，点击这里查看本话题的所有回帖 | |||
[资源]
《Phase Transitions in Polymers》（程正迪先生2008年的专著）
|
|||
|
Phase Transitions in Polymers: The Role of Metastable States The Role of Metastable States Copyright © 2008 Elsevier B.V. All rights reserved Author(s): Stephen Z.D. Cheng Description A classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are kinetically impeded on the pathway to thermodynamic equilibrium. This was illustrated in structural and morphological investigations of crystallization and mesophase transitions, liquid-liquid phase separation, vitrification and gel formation, as well as combinations of these transformation processes. The phase behaviours in polymers are thus dominated by interlinks of metastable states on different length scales. This concept successfully explains many experimental observations and provides a new way to connect different aspects of polymer physics. Contents Foreword. Preface. 1. Introduction. 1.1. Phases in single component systems. 1.2. Phase transitions in single component systems. 2. Thermodynamics and kinetics of phase transitions. 2.1. Thermodynamics of phase transitions in single component systems. 2.2. Kinetic aspects of phase transitions in single component systems. 2.3. Phase and phase transitions in mutiple component systems. 3. Concepts of metastable states. 3.1. Ostwald?s stage rule and definition of a metastable state. 3.2. Examples of metastable states in phase transitions. 3.3. Appearance of metastable states controlled by competing kinetics. 3.4. What are the limitations of this concept? 3.5. Concept of metastability. 4. Metastable states in phase transitions of polymers. 4.1. Supercooled liquids and crystallization. 4.2. Superheated crystals and crystal melting. 4.3. Metastable states in phase separated polymer mixtures and copolymers. 5. Metastable states observed due to phase transformation kinetics in polymers. 5.1. Appearance of metastable states based on their crystal nucleation barriers. 5.2. Polymorphs and their competing formation kientics. 5.3. Monotropic phase transitions in polymers. 5.4. Environment induced metastable phases. 6. Interdependence of metastable states on different length scales in polymers. 6.1. Combining phase size effect with polymorphs. 6.2. Liquid-liquid phase separation coupled with vitrification. 6.3. Liquid-liquid phase separation coupled with crystallization. 6.4. Liquid-liquid phase separation associated with gelation and crystallization. 7. Outlook - A personal view. Index. 下载地址： http://www.filefactory.com/file/715651/n/0444519114_rar http://rapidshare.com/files/149069889/0444519114.rar [ Last edited by zhanghd on 2008-10-5 at 23:33 ] |
回复此楼» 收录本帖的淘帖专辑推荐
 100%研究生 |
» 猜你喜欢
求调剂 有机化学考研356分
已经有4人回复
-
0703 化学 求调剂，一志愿山东大学 342 分
已经有4人回复
-
086000生物与医药调剂
已经有7人回复
-
305求调剂
已经有7人回复
-
348求调剂
已经有3人回复
-
332求调剂
已经有6人回复
-
各位老师好，我的一志愿为北京科技大学085601材料专硕
已经有6人回复
-
085600 材料与化工 329分求调剂
已经有10人回复
-
356求调剂
已经有3人回复
-
一志愿武汉理工，总分321，英一数二，求老师收留。
已经有7人回复
14楼2009-01-22 14:00:40
3楼2008-09-09 20:41:04
5楼2008-09-24 23:54:45
6楼2008-09-25 08:36:58
