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Chempricess新虫 (小有名气)
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[求助]
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One is the Felkin-Ahn model, which emphasizes stabilization of the developing negative charge in the forming bond by interaction with the ∗ orbital of the substituent. The Cieplak model263 emphasizes an alternative interaction in which the orbital of the C−X bond acts as a donor to the developing antibonding orbital.264 |
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感谢参与，应助指数 +1
Chempricess: 金币+20, ★★★★★最佳答案 2015-09-28 14:44:36
感谢参与，应助指数 +1
Chempricess: 金币+20, ★★★★★最佳答案 2015-09-28 14:44:36
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One is the Felkin-Ahn model, which emphasizes stabilization of the developing negative charge in the forming bond by interaction with the ∗ orbital of the substituent. The Cieplak model263 emphasizes an alternative interaction in which the orbital of the C−X bond acts as a donor to the developing antibonding orbital.264 一个是 Felkin-Ahn 模型, 它强调的是在所形成的键中，通过和取代基的∗轨道的相互作用所产生的负电荷的稳定性。 Cieplak 模型l263，它强调的是另一种相互作用， 在这种作用中，C−X键的轨道是所形成的反键轨道264的（电子）供体。 |
2楼2015-09-28 14:40:35