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A similar compartmental complex [Cu(H2C16H20O4N2)] involving the coordination of N has been used for purposes of comparison.In the molecular structure of [Cu(H2C16H20O4N2)], the compartmental ligand is6,11-dimethyl-7,10-diazahexadeca-5,11-diene-2,4,13,15-tetraene (H4daaen), a copper ion is coordinated by two N atoms, and the binding energy of Cu 2p3/2 is 934.5 eV, which is approximately 1.2 eV greater than that of the product of our experiment. »¹ÓÐ(H4daaen)Õâ¸öÊÇɶ°¡£¬Ð»Ð» |
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