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The results revealed that the flux of the NaCl solutions and pure water through the geopolymer circular plate membrane is nearly zero, whereas the flux of the NaCl solutions through the self-supporting zeolite membrane can be greater than 4.74 kg m-2 h-1 (25ºC) when the membrane thickness was decreased to 2 mm (see Fig. 6). In this membrane, the majority of the geopolymer gel was converted into the zeolite phase after the hydrothermal process (see Fig. 2 and Fig. 3), whereas a small quantity of non-converted material inside the membrane continued to provide strength and buttressing support for the zeolite membrane. The flux through the suddenly changed geopolymer primarily resulted from the transformation of the micropores in the geopolymer gel. The volume of the micropores changed from 0 to 0.049 cc/g after the hydrothermal process. The pervaporation temperature was maintained at approximately 25ºC, and the feed pressure was less than 0.1 MPa depending on the pervaporation temperature. During the pervaporation process for the desalination of seawater, the disc-shaped NaA zeolite membrane (diameter = 40 mm, thickness = 2-10 mm) was sealed in a membrane module. The feed was usually placed on the zeolite side of the support to minimize the concentration polarization. The concentration of Na ions in the collected permeated solutions was analyzed using ICP to obtain the ion % rejection value. |
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