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hanamichi木虫 (小有名气)
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JACS精选文章: Glowing Long with Sub-10 nm Rechargeable Luminous Pearls已有2人参与
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文题为：Direct Aqueous-Phase Synthesis of Sub-10 nm “Luminous Pearls” with Enhanced in Vivo Renewable Near-Infrared Persistent Luminescence 由UMass Medical School的Gang Han课题组发表。该文章被JACS Spotlights报道，并且被选为ACS Editors' Choice. 该文可以免费获取阅读权限： http://dx.doi.org/10.1021/jacs.5b00872 以下链接是JACS Spotlights对该文的报道： http://dx.doi.org/10.1021/jacs.5b04394  以下是文章摘要： Near-infrared (NIR) persistent luminescence nanoparticles (PLNPs), possessing unique NIR PL properties, have recently emerged as important materials for a wide variety of applications in chemistry and biology, for which they must endure high-temperature solid-state annealing reactions and subsequent complicated physical post-treatments. Herein, we report on a first direct aqueous-phase chemical synthesis route to NIR PLNPs and present their enhanced in vivo renewable NIR PL. Our method leads to monodisperse PLNPs as small as ca. 8 nm. Such sub-10 nm nanocrystals are readily dispersed and functionalized, and can form stable colloidal solutions in aqueous solution and cell culture medium for biological applications. Under biotissue-penetrable red-light excitation, we found that such nanocrystals possess superior renewable PL photoluminescence in vitro and in vivo compared to their larger counterparts currently made by existing methods. We believe that this solid-state-reaction-free chemical approach overcomes the current key roadblock in regard to PLNP development, and thus will pave the way to broad use of these advanced miniature “luminous pearls” in photonics and biophotonics. |
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2楼2015-06-13 16:14:13
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3楼2015-06-13 17:48:34