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xieliting

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13C NMR (126 MHz, DMSO) δ
14.11,14.76,16.50,17.12,18.32,22.89,28.51,29.84,30.95,31.19,31.66,32.27,36.37,39.04,39.20,39.37,39.54,39.71,39.80,39.87,40.04,41.14,41.57,42.56,49.54,56.36,62.25,65.66,65.92,66.85,67.91,69.19,69.49,70.34,70.55,71.02,71.18, 72.16, 73.18,76.69,80.21,82.75,84.30,98.67,99.82,105.11,108.45,123.78,138.83

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yangyinhe

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【答案】应助回帖

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感谢参与,应助指数 +1
xieliting: 金币+8, 有帮助 2015-06-04 19:22:06
xieliting(卓越_先锋代发): 金币+12 2015-06-05 13:10:17
1 .     Compound 2a
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Structure      13C NMR    Structure & 13C NMR     碳谱模拟图

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2 .     ruscogenin l-O-{ O-β-D-glucopyranosyl-(1-3)-O-α-L-rhamnopyransol-(1→2)-4,6-di-O-acetyl-β-D-gaiactopyranoside}
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4 .     (25R)-ruscogenin 1-O-[2-O-(acetyl)-α-L-rhamnopyranosyl-(1→2)][β-D-xylopyranosyl-(1→3)]-β-D-fucopyranoside
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5 .     (25R)-3β-hydroxyspirost-5-en-1β-yl O-α-L-rhamnopyranosyl-(1→2)-O-[β-D-xylopyranosyl-(1→3)]-6-O-acetyl-β-D-galactopyranoside
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6 .     (25S)-ruscogenin 1-O-{O-β-D-glucopyranosyl-(1→3)-O-α-L-rhamnopyranosyl-(1→2)-O-[β-D-xylopyranosyl-(1→3)]-β-D-glucopyranoside}
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8 .     3-O-[α-L-rhamnopyranosyl(1→3)-α-L-arabinopyranosyl(1→3)-β-D-xylopyranosyl(1→3)-β-D-glucopyranosyl]-25R,5α-spirostan-2α,3β-diol
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