24小时热门版块排行榜

返回列表

zhaolun

新虫 (初入文坛)

应助: 0 (幼儿园)
金币: 267.5
帖子: 21
在线: 77.4小时
虫号: 635109
注册: 2008-10-24
专业: 有机合成

[求助] 本人新手,得到的实验数据一头雾水.请高人帮忙分析下数据,并画一下孔径分布图. 已有1人参与

Quantachrome Instruments
                  Quantachrome Autosorb Automated Gas Sorption System Report
                                 Autosorb 1 for Windows  1.55

File name:    C:\QCdata\PhysData\LZF-150407-1.raw
Sample ID:    2015-4-9       Description: blue
Comments:
Operator:    QU             Sample weight: 0.1238 g
Analysis gas:  Nitrogen       X sect. area:  16.2 挪/molec    Non-ideality:  6.58e-05
Adsbate (DRP): Nitrogen       Bath Temp.: 77.30
Outgas Temp: 25.0  癈       Outgas Time: 30.0  hrs       Analysis Time: 183.1 min
P/Po tolerance: 3             Equil. time: 2                End of run: 04/09/2015 19:35
Station #:    1                PC sw. version: 1.55          TempComp:    Off

                                 Isotherm

  P/Po    Volume          P/Po    Volume          P/Po    Volume
         [cc/g] STP                [cc/g] STP                [cc/g] STP

6.0379e-02 0.5054       7.0992e-01 1.6794       6.3889e-01 1.7628
1.1147e-01 0.6156       7.5983e-01 1.7648       5.8860e-01 1.6798
1.6129e-01 0.7310       8.0942e-01 1.9389       5.3874e-01 1.5431
2.1121e-01 0.8147       8.5896e-01 2.2152       4.8838e-01 1.4019
2.6106e-01 0.9136       9.0871e-01 2.5155       4.3836e-01 1.3209
3.1098e-01 1.0011       9.5766e-01 3.1698       3.8844e-01 1.1974
3.6077e-01 1.1072       9.9940e-01 4.9737       3.3835e-01 1.1266
4.1088e-01 1.1514       9.4154e-01 3.3162       2.8841e-01 1.0076
4.6057e-01 1.2473       8.8948e-01 2.8014       2.3842e-01 0.8873
5.1063e-01 1.3030       8.3935e-01 2.4703       1.8838e-01 0.7764
5.6035e-01 1.4153       7.8916e-01 2.2106       1.3839e-01 0.6780
6.1029e-01 1.4886       7.3876e-01 2.0892       8.8382e-02 0.5658
6.6002e-01 1.5911       6.8889e-01 1.9359       4.0007e-02 0.4615

04/10/2015
                                    Quantachrome Instruments
                  Quantachrome Autosorb Automated Gas Sorption System Report
                                 Autosorb 1 for Windows  1.55

File name:    C:\QCdata\PhysData\LZF-150407-1.raw
Sample ID:    2015-4-9       Description: blue
Comments:
Operator:    QU             Sample weight: 0.1238 g
Analysis gas:  Nitrogen       X sect. area:  16.2 挪/molec    Non-ideality:  6.58e-05
Adsbate (DRP): Nitrogen       Bath Temp.: 77.30
Outgas Temp: 25.0  癈       Outgas Time: 30.0  hrs       Analysis Time: 183.1 min
P/Po tolerance: 3             Equil. time: 2                End of run: 04/09/2015 19:35
Station #:    1                PC sw. version: 1.55          TempComp:    Off

                     AREA-VOLUME-PORE SIZE SUMMARY

                              SURFACE AREA DATA

Multipoint BET..............................................  3.270E+00  m?g
Single Point BET............................................  3.002E+00  m?g
BJH Method Cumulative Adsorption Surface Area...............  4.280E+00  m?g
BJH Method Cumulative Desorption Surface Area...............  4.597E+00  m?g
DH Method Cumulative Adsorption Surface Area................  4.403E+00  m?g
DH Method Cumulative Desorption Surface Area................  4.707E+00  m?g

                              PORE VOLUME DATA

Total Pore Volume for pores with Radius
less than 15958.6 ?at P/Po = 0.99940.......................  7.712E-03  cc/g
BJH Method Cumulative Adsorption Pore Volume................  8.182E-03  cc/g
BJH Method Cumulative Desorption Pore Volume................  8.291E-03  cc/g
BJH Interpolated Cumulative Adsorption Pore Volume for pores
in the range of 5000.0 to 0.0 ?Radius......................  7.084E-03  cc/g
BJH Interpolated Cumulative Desorption Pore Volume for pores
in the range of 5000.0 to 0.0 ?Radius......................  7.294E-03  cc/g
DH Method Cumulative Adsorption Pore Volume.................  7.957E-03  cc/g
DH Method Cumulative Desorption Pore Volume.................  8.066E-03  cc/g

                              PORE SIZE DATA

Average Pore Radius  .......................................  4.717E+01  ?
BJH Method Adsorption Pore Radius (Mode)..................  8.741E+00  ?
BJH Method Desorption Pore Radius (Mode)..................  1.196E+01  ?
DH  Method Adsorption Pore Radius (Mode)..................  8.741E+00  ?
DH  Method Desorption Pore Radius (Mode)..................  1.196E+01  ?

                        DATA REDUCTION PARAMETERS

                        Thermal Transpiration : OFF
                     Last Po Acquired 512.00 mm Hg
                              MaxiDose : ON
                           Initial Fill : OFF
                              DoseWizard : OFF

                     BJH/DH Moving Average Size : 0
                        Thickness method : DeBoer

               Interaction Constant (K) 0.0000 nm^3 x kJ/mol

                        ADSORBATE MODEL PARAMETERS

                        Adsorbate Type = Nitrogen
                     Adsorbate Temp. = 77.3500 K
                     Molecular Weight = 28.0134 g/mol
                     Cross-Sect. Area = 16.2000 挪/molecule
                        Liquid Density = 0.8060 g/cc
                        Critical Temp. = 126.2000 K
                     Critical Pressure = 33.5000 atm
                     Average Diameter = 0.3000 nm
                        Polarizability = 1.4600 (cc/molec) x 1e-24
                     Magnetic Suscept. = 2.0000 (cc/molec) x 1e-29
                     Molecular Density = 6.7000 (molec/cm? x 1e14
                     Surface Tension = 8.8500 erg/cm?
                        Contact Angle = 0.0000 degrees
         Supercritical Ads. Constant K = 1.0000

                        ADSORBENT MODEL PARAMETERS

                        Adsorbent Type = Carbon
                        Atom Diameter = 0.3400 nm
                        Polarizability = 1.0200 (cc/molecule) x 1e-24
                     Magnetic Suscept. = 13.5000 (cc/molecule) x 1e-29
                  Surface Atom Density = 38.4500 (molec/cm? x 1e14
                     Adsorbent Density = 2.2460 g/cc
                     DR exponent (n) = 2.0000
04/10/2015
                                    Quantachrome Instruments
                  Quantachrome Autosorb Automated Gas Sorption System Report
                                 Autosorb 1 for Windows  1.55

File name:    C:\QCdata\PhysData\LZF-150407-1.raw
Sample ID:    2015-4-9       Description: blue
Comments:
Operator:    QU             Sample weight: 0.1238 g
Analysis gas:  Nitrogen       X sect. area:  16.2 挪/molec    Non-ideality:  6.58e-05
Adsbate (DRP): Nitrogen       Bath Temp.: 77.30
Outgas Temp: 25.0  癈       Outgas Time: 30.0  hrs       Analysis Time: 183.1 min
P/Po tolerance: 3             Equil. time: 2                End of run: 04/09/2015 19:35
Station #:    1                PC sw. version: 1.55          TempComp:    Off

                     BJH ADSORPTION PORE SIZE DISTRIBUTION

Radius  Pore Vol  Pore Surf Area Dv(r)    Ds(r)    Dv(log r)  Ds(log r)
?    [cc/g]    [m?g]    [cc/?g] [m??g] [cc/g]    [m?g]

7.44  1.523E-04 4.095E-01 1.106E-04  2.975E-01  1.889E-03  5.080E+00
8.74  4.363E-04 1.059E+00 2.306E-04  5.275E-01  4.633E-03  1.060E+01
9.98  6.010E-04 1.390E+00 1.332E-04  2.671E-01  3.056E-03  6.127E+00
11.24  8.527E-04 1.837E+00 1.951E-04  3.472E-01  5.043E-03  8.974E+00
12.58  1.063E-03 2.172E+00 1.515E-04  2.409E-01  4.384E-03  6.970E+00
14.04  1.354E-03 2.586E+00 1.904E-04  2.713E-01  6.149E-03  8.761E+00
15.66  1.404E-03 2.651E+00 2.918E-05  3.726E-02  1.051E-03  1.342E+00
17.50  1.641E-03 2.921E+00 1.210E-04  1.382E-01  4.869E-03  5.564E+00
19.63  1.733E-03 3.015E+00 3.995E-05  4.069E-02  1.804E-03  1.837E+00
22.15  2.006E-03 3.261E+00 9.984E-05  9.015E-02  5.086E-03  4.592E+00
25.19  2.148E-03 3.374E+00 4.249E-05  3.373E-02  2.461E-03  1.954E+00
28.99  2.369E-03 3.527E+00 5.219E-05  3.601E-02  3.477E-03  2.399E+00
33.88  2.539E-03 3.627E+00 3.046E-05  1.798E-02  2.371E-03  1.400E+00
40.52  2.687E-03 3.700E+00 1.928E-05  9.518E-03  1.794E-03  8.854E-01
50.08  3.040E-03 3.841E+00 3.094E-05  1.236E-02  3.553E-03  1.419E+00
65.27  3.606E-03 4.014E+00 2.982E-05  9.138E-03  4.450E-03  1.364E+00
94.14  4.184E-03 4.137E+00 1.491E-05  3.167E-03  3.185E-03  6.766E-01
  175.45  5.374E-03 4.273E+00 9.610E-06  1.095E-03  3.715E-03  4.235E-01
8098.00  8.182E-03 4.280E+00 1.786E-07  4.412E-07  1.537E-03  3.795E-03
04/10/2015
                                    Quantachrome Instruments
                  Quantachrome Autosorb Automated Gas Sorption System Report
                                 Autosorb 1 for Windows  1.55

File name:    C:\QCdata\PhysData\LZF-150407-1.raw
Sample ID:    2015-4-9       Description: blue
Comments:
Operator:    QU             Sample weight: 0.1238 g
Analysis gas:  Nitrogen       X sect. area:  16.2 挪/molec    Non-ideality:  6.58e-05
Adsbate (DRP): Nitrogen       Bath Temp.: 77.30
Outgas Temp: 25.0  癈       Outgas Time: 30.0  hrs       Analysis Time: 183.1 min
P/Po tolerance: 3             Equil. time: 2                End of run: 04/09/2015 19:35
Station #:    1                PC sw. version: 1.55          TempComp:    Off

                     BJH DESORPTION PORE SIZE DISTRIBUTION

Radius  Pore Vol  Pore Surf Area Dv(r)    Ds(r)    Dv(log r)  Ds(log r)
?    [cc/g]    [m?g]    [cc/?g] [m??g] [cc/g]    [m?g]

6.81  0.000E+00 0.000E+00 0.000E+00  0.000E+00  0.000E+00  0.000E+00
8.16  1.694E-04 4.152E-01 1.339E-04  3.280E-01  2.511E-03  6.152E+00
9.41  3.280E-04 7.522E-01 1.291E-04  2.744E-01  2.793E-03  5.936E+00
10.66  5.725E-04 1.211E+00 1.934E-04  3.631E-01  4.740E-03  8.898E+00
11.96  8.733E-04 1.714E+00 2.240E-04  3.746E-01  6.161E-03  1.030E+01
13.36  1.176E-03 2.168E+00 2.073E-04  3.103E-01  6.372E-03  9.538E+00
14.91  1.289E-03 2.319E+00 6.895E-05  9.249E-02  2.364E-03  3.172E+00
16.65  1.596E-03 2.687E+00 1.662E-04  1.997E-01  6.365E-03  7.646E+00
18.64  1.747E-03 2.849E+00 7.049E-05  7.563E-02  3.023E-03  3.243E+00
20.99  2.093E-03 3.179E+00 1.356E-04  1.292E-01  6.545E-03  6.237E+00
23.79  2.418E-03 3.452E+00 1.062E-04  8.926E-02  5.811E-03  4.884E+00
27.25  2.569E-03 3.563E+00 3.919E-05  2.876E-02  2.455E-03  1.802E+00
31.65  2.967E-03 3.815E+00 8.063E-05  5.096E-02  5.864E-03  3.706E+00
37.45  3.298E-03 3.992E+00 4.963E-05  2.650E-02  4.269E-03  2.280E+00
45.65  3.530E-03 4.093E+00 2.382E-05  1.044E-02  2.494E-03  1.093E+00
58.20  4.071E-03 4.279E+00 3.519E-05  1.209E-02  4.689E-03  1.611E+00
80.21  4.737E-03 4.445E+00 2.326E-05  5.801E-03  4.250E-03  1.060E+00
  134.29  5.711E-03 4.590E+00 1.225E-05  1.824E-03  3.673E-03  5.471E-01
8066.33  8.291E-03 4.597E+00 1.634E-07  4.053E-07  1.315E-03  3.260E-03

无标题.jpg

回复此楼