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1.Polymer Surfaces and Interfaces
Manfred Stamm
Surfaces and interfaces of polymers play an important role, both for basic mate-rials science as well as for the design and development of applications. If one reflects more closely about it, nearly all aspects of polymer research and applica-tion are directly or indirectly connected with surface andinterface phenomena. So polymers are in large quantities applied as coatings and thin films, where of course the appearance, durability and stability depends on the surface and interface prop-rties. But similarly bulk applications require smooth, coloured or scratch resistant surfaces, to name only some of the surface properties, and also the properties in he bulk like toughness or impact resistance of polymers are connected with defect, void or crack formation, which involves internal interfaces. .
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2£¬Interphases and Mesophases in Polymer Crsytallization I
Polymer crystallisation is a field of science whose widespread practical and
technological implications add to its scientific relevance. Unlike mostmolecu-
lar substances, synthetic polymers consist of long, linear chains usually cover-
ing a broad distribution of molecular lengths. It is no surprise that only rarely
may they give rise to regularly shaped crystals, if at all. As a rule, especially
from the bulk state, polymers solidify as very tiny crystals interspersed in an
amorphous matrix and randomly interconnected by disordered chains. How
do these crystals form? Do they correspond to a state of thermodynamic equi-
librium, or are the chains so inextricably entangled that equilibriumis virtually
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