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| δC(CDCl3): 14.19,19.66,31.05,50.22,56.41,57.01,66.04,71.00,84.43,109.22,109.92,114.61,119.82,121.64,129.32,131.37,134.43,146.03,152.57,168.18. |
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???????????鵽740????????(???????????ο?) 1 . erythro-1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxy-4-(1(E)-prophenyl)phenoxy)-propan-1-ol ?????:75% Natural Product Research and Development 2010 22 987-990 Chemical Constituents of Myristica argentea Warb. SHI Ji; ZHAO Qi-miao; JIA Tia-zhu Structure 13C NMR Structure & 13C NMR ??????? 2 . major-(??)-7-(4-Methoxy-benzyloxymethyl)-8-triisopropylsilanyloxy-7,8-dihydro-6H-[1,3]dioxol-[4,5-g]-isoquinolin-5-one C28H39NO6Si ?????:75% Journal of the Brazilian Chemical Society 2007 18 1415-1438 Studies Toward the Synthesis of Amaryllidaceae Alkaloids from Morita-Baylis-Hillman Adducts. A Straightforward Synthesis of Functionalized Dihydroisoquinolin-5(6H)-one Core Elizandra C.S. Lopes and Fernando Coelho Structure 13C NMR Structure & 13C NMR ??????? 3 . compound 11 ?????:71.4% Natural Product Research 1994 4 65-72 Syntheses of Strychnos and Aspidospermatan Type Alkaloids. 4. Formation of the Pentacyclic Core by an Intramolecular Diels Alder Reaction M. E. Kuehne; C. S. Brook; D. A. Frasier Structure 13C NMR Structure & 13C NMR ??????? 4 . odoratisol B C20H24O5 ?????:70% Chemical & Pharmaceutical Bulletin 2006 54(3) 380-383 New Neolignans and Lignans from Vietnamese Medicinal Plant Machilus odoratissima NEES PHAN Minh Giang,PHAN Tong Son,Katsuyoshi MATSUNAMI,and Hideaki OTSUKA Structure 13C NMR Structure & 13C NMR ??????? 5 . denudadione C C20H20O5 ?????:70% Chemical & Pharmaceutical Bulletin 2000 48(6) 832-837 Bicyclo[3.2.1]octane and 6-Oxabicyclo[3.2.2]nonane Type Neolignans form Magnolia denudata Masanori KUROYANGGI,Kenichi YOSHIDA,Atsushi YAMAMOTO,and Masao MiWA Structure 13C NMR Structure & 13C NMR ??????? 6 . (-)-berchemol C26H30O10 ?????:70% Chemical & Pharmaceutical Bulletin 1989 37 3311-3315 A New Lignan, (-)-Berchemol, from Berchemia racemosa Nobuko SAKURAI,Shin-ichi NAGASHIMA,Ken-ichi KAWAI and Takao INOUE Structure 13C NMR Structure & 13C NMR ??????? 7 . taxiresinol ?????:70% Phytochemistry 1999 50 147-149 A lignan from Daphne oleoides Nisar Ullah, Saeed Ahmad, Erum Anis, Pir Mohammad, Hafiz Rabnawaz, Abdul Malik Structure 13C NMR Structure & 13C NMR ??????? 8 . Threo-2,3-bis(4-hydroxy-3-methoxyphenyl)-3-butoxypropan-1-ol C21H28O6 ?????:70% Phytochemistry Letters 2012 5 59-62 New phenolics from the wood of Casearia grewiifolia Kanok-on Rayanil,Chanisara Nimnoun,Pittaya Tuntiwachwuttikul Structure 13C NMR Structure & 13C NMR ??????? 9 . 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Compound 4 ?????:70% Bioorganic & Medicinal Chemistry Letters 2007 17 4128-4130 R-(− -N-alkyl-11-hydroxy-10-hydroxymethyl- and 10-methyl-aporphines as 5-HT1A receptor ligands Yu-Gui Si, Matthew P. Gardner, Frank I. Tarazi, Ross J. Baldessarini, John L. Neumeyer Structure 13C NMR Structure & 13C NMR ??????? 15 . (2S,3R)-trans-3-acetoxy-3',4'-dimethoxyflavan C19H20O5 ?????:70% Bioorganic & Medicinal Chemistry 2009 17 7156-7173 Synthesis and biological evaluation of flavan-3-ol derivatives as positive modulators of GABAA receptors Kenneth N. Mewett, Sebastian P. Fernandez, Anmol K. Pasricha, Alice Pong, Steven O. Devenish, David E. Hibbs, Mary Chebib, Graham A.R. Johnston, Jane R. Hanrahan Structure 13C NMR Structure & 13C NMR ??????? 16 . (2S,3R)-trans-3-acetoxy-3'-bromo-4',5'-dimethoxyflavan C19H19BrO5 ?????:70% Bioorganic & Medicinal Chemistry 2009 17 7156-7173 Synthesis and biological evaluation of flavan-3-ol derivatives as positive modulators of GABAA receptors Kenneth N. Mewett, Sebastian P. Fernandez, Anmol K. Pasricha, Alice Pong, Steven O. Devenish, David E. Hibbs, Mary Chebib, Graham A.R. Johnston, Jane R. Hanrahan Structure 13C NMR Structure & 13C NMR ??????? 17 . 3,3'-dimethoxy-4,4',9-trihydroxy-7,9'-epoxylignan-7'-one C20H22O7 ?????:70% Journal of the Chinese Chemical Society 1999 46 811-818 Lignans, Flavonoids and Phenolic Derivatives from Taxus mairei ????(Shung-Jim Yang);??????(Jim-Min Fang);?????(Yu-Shia Cheng) Structure 13C NMR Structure & 13C NMR ??????? 18 . 3,3a,4,9b-tetrahydro-3-(3,4-dimethoxyphenyl)-1-methyl-1H-chromeno[4,3-c]isoxazole-3a-carbonitrile C20H20N2O4 ?????:70% European Journal of Organic Chemistry 2010 5825-5830 Highly Stereoselective Synthesis of Tricyclic Chromenoisoxazolidines by Intramolecular 1,3-Dipolar Cycloadditions Manickam Bakthadoss and Gandhi Murugan Structure 13C NMR Structure & 13C NMR ??????? 19 . methyl (2E)-5-[N-(3,4-dimethoxyphenyl)-4-methylphenylsulfonamido]-2-pentenoate C21H25NO6S ?????:70% Tetrahedron 2013 69 4120-4138 Novel method for construction of tetrahydro-1-benzazepine and tetrahydro-2-benzazepine based on 7-endo selective Friedel?CCrafts cyclization of vinyloxirane Megumi Mizukami, Koji Wada, Gen Sato, Yusuke Ishii, Norio Kawahara, Shinji Nagumo Structure 13C NMR Structure & 13C NMR ??????? 20 . methyl 2-(4-butoxyphenylsulfonamido)-3-(1H-indol-3-yl)propanoate C22H26N2O5S ?????:70% Bioorganic & Medicinal Chemistry 2013 21 6466-6476 Design and bio-evaluation of indole derivatives as potent Kv1.5 inhibitors Xiaoke Guo, Qian Yang, Jing Xu, Li Zhang, Hongxi Chu, Peng Yu, Yingying Zhu, Jinglian Wei, Weilin Chen, Yaozhong Zhang, Xiaojin Zhang, Haopeng Sun, Yiqun Tang, Qidong You Structure 13C NMR Structure & 13C NMR ??????? 21 . coniferylferulate ?????:70% China Journal of Chinese Materia Medica 2014 39 80-82 A new phthalide from Angelicae Sinensis Radix NIU Yan, WANG Shu-fang Structure 13C NMR Structure & 13C NMR ??????? 22 . compound NT17 ?????:70% Natural Product Communications 2010 5 755-762 Computer-aided Structure Elucidation of Neolignans Mara B. Costantin, Marcelo J. P. Ferreira, Gilberto V. Rodrigues and Vicente P. Emerenciano Structure 13C NMR Structure & 13C NMR ??????? 23 . minor-(??)-7-(4-Methoxy-benzyloxymethyl)-8-triisopropylsilanyloxy-7,8-dihydro-6H-[1,3]dioxol-[4,5-g]-isoquinolin-5-one C28H39NO6Si ?????:70% Journal of the Brazilian Chemical Society 2007 18 1415-1438 Studies Toward the Synthesis of Amaryllidaceae Alkaloids from Morita-Baylis-Hillman Adducts. A Straightforward Synthesis of Functionalized Dihydroisoquinolin-5(6H)-one Core Elizandra C.S. Lopes and Fernando Coelho Structure 13C NMR Structure & 13C NMR ??????? 24 . (S)-3-(2,5-Dimethoxy-4-methylphenoxy)-2-hydroxy-3-methylbutyl-4-methylbenzenesulfonate C21H28O7S ?????:70% The Journal of Organic Chemistry 2012 77 8231-8243 Total Synthesis of Natural Enantiomers of Heliespirones A and C via the Diastereoselective Intramolecular Hosomi-Sakurai Reaction Akari Miyawaki, Daisuke Kikuchi, Masu Niki, Yuki Manabe, Makoto Kanematsu, Hiromasa Yokoe, Masahiro Yoshida, and Kozo Shishido Structure 13C NMR Structure & 13C NMR ??????? |

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-N-alkyl-11-hydroxy-10-hydroxymethyl- and 10-methyl-aporphines as 5-HT1A receptor ligands