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[资源] 2005年Physical Chemistry (Instant Notes)

Abbreviations ix
Preface xi
Section A— States of matter 1
A1 Perfect gases 2
A2 Molecular behavior in perfect gases 6
A3 Non-ideal gases 11
A4 Liquids 16
A5 Crystalline solids 22
A6 Diffraction by solids 28
Section B— Thermodynamics 34
B1 The first law 35
B2 Enthalpy 41
B3 Thermochemistry 44
B4 Entropy 50
B5 Entropy and change 55
B6 Free energy 59
Section C— Equilibria 64
C1 Fundamentals of equilibria 65
C2 Fundamentals of acids and bases 74
C3 Further acids and bases 77
C4 Acid-base titrations 82
C5 Solubility 87
Section D— Solutions 91
D1 Non-electrolyte solutions 92
D2 Solutions 95
D3 Colligative properties 97
D4 Phase equilibria 102
D5 Phase diagrams of mixtures 107
Section E— Ionic solutions 118
E1 Ions in aqueous solution 119
E2 Thermodynamics of ions in solution 123
E3 Electrochemical cells 127
E4 Electrochemical thermodynamics 131
E5 Electrochemistry and ion concentration 137
E6 Macroscopic aspects of ionic motion 142
E7 Molecular aspects of ionic motion 147
E8 The motion of larger ions 150
Section F— Kinetics 154
F1 Empirical approaches to kinetics 155
F2 Rate law determination 162
F3 Energetics and mechanisms 171
F4 Formulation of rate laws 179
F5 Rate laws in action 184
F6 The kinetics of real systems 192
Section G— Quantum nature of the physical world 201
G1 Nuclear structure 202
G2 Applications of nuclear structure 207
G3 Quantization of energy and particle-wave duality 212
G4 The wave nature of matter 220
G5 The structure of the hydrogen atom 231
G6 Many-electron atoms 240
G7 Chemical and structural effects of quantization 246
G8 Statistical thermodynamics 252
Section H— Bonding 259
H1 Elementary valence theory 260
H2 Valence bond theory 265
H3 Molecular orbital theory of diatomic molecules I 271
H4 Molecular orbital theory of diatomic molecules II 277
H5 Strong solid phase interactions 287
H6 Weak intermolecular interactions 295
Section I— Spectroscopy 303
I1 General features of spectroscopy 304
I2 Practical aspects of spectroscopy 309
I3 Rotational spectroscopy 315
I4 Vibrational spectroscopy 322
I5 Applied vibrational spectroscopy 327
I6 Electronic spectroscopy 333
I7 Photochemistry in the real world 339
I8 Magnetic resonance spectroscopy 344
Appendix— mathematical relations 353
Further reading 356
Index 360

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2015-02-26 19:55:07, 4.93 M