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Introduction to surface chemistry and catalysis Second Edition
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这是伯克利大学Gabor Somorjai的大作的第二版，相比于第一版，在原理上讲得更多了一些，而且有一些新进的进展也包括在内。应该算是首发，不知道有没有奖励！ 这个老爷爷人很好，不获诺贝尔奖有点遗憾。 在小木虫获益良多，这是一个回馈的机会，但是现在的感觉是书太多，资料太多，你根本看不过来。 Enjoy PREFACE INTRODUCTION 1 SURFACES: AN INTRODUCTION 1.1 HISTORICAL PERSPECTIVE 1.2 SURFACES AND INTERFACES: CLASSIFICATION OF PROPERTIES 1.3 EXTERNAL SURFACES 1.4 CLEAN SURFACES 1.5 INTERFACES 1.6 THE TECHNIQUES OF SURFACE SCIENCE 1.7 SUMMARY AND CONCEPTS 1.8 PROBLEMS 2 THE STRUCTURE OF SURFACES 2.1 INTRODUCTION 2.2 SURFACE DIFFRACTION 2.3 NOTATION OF SURFACE STRUCTURES 2.4 THE STRUCTURE OF CLEAN SURFACES 2.5 RECONSTRUCTION 2.6 THE STRUCTURE OF ADSORBED MONOLAYERS 2.7 POLYMER SURFACES 2.8 SUMMARY AND CONCEPTS 2.9 PROBLEMS 3 THERMODYNAMICS OF SURFACES 3.1 INTRODUCTION 3.2 DEFINITION OF SURFACE THERMODYNAMIC FUNCTIONS 3.3 WORK NEEDED TO CREATE A SURFACE OF A ONE-COMPONENT SYSTEM: SURFACE TENSION 3.4 THE SURFACE ENERGY AND SURFACE COMPOSITION OF TWO-COMPONENT SYSTEMS 3.5 SURFACES WHEN NO BULK PHASE EXISTS: TWO-DIMENSIONAL PHASES 3.6 METASTABLE SURFACE PHASES 3.7 CURVED SURFACES 3.8 THERMODYNAMICS OF ADSORBED MONOLAYERS 3.9 THERMAL STABILITY OF SURFACE LAYER AND NANOCRYSTALS 3.10 THERMAL STABILITY OF SURFACE OXIDE LAYER 3.11 SUMMARY AND CONCEPTS 3.12 PROBLEMS 4 DYNAMICS AT SURFACES 4.1 INTRODUCTION 4.2 SURFACE ATOM VIBRATIONS 4.3 ELEMENTARY PROCESSES OF GAS– SURFACE INTERACTION 4.4 ADSORPTION 4.5 SURFACE DIFFUSION 4.6 DESORPTION 4.7 SUMMARY AND CONCEPTS 4.8 PROBLEMS 5 ELECTRICAL PROPERTIES OF SURFACES 5.1 INTRODUCTION 5.2 THE ELECTRON DENSITY DISTRIBUTION AT THE SURFACE AND THE INTERFACE DIPOLE LAYER 5.3 THE SURFACE ELECTRON POTENTIAL 5.4 THE WORK FUNCTION 5.5 THE SURFACE ENERGY 5.6 THE SURFACE DIPOLE LAYER 5.7 ADSORPTION-INDUCED CHARGE TRANSFER AT SURFACES: METALS AND INSULATORS 5.8 SURFACE ELECTRON DENSITY OF STATES 5.9 ELECTRON EXCITATION AT SURFACES 5.10 ELECTRON TUNNELING 5.11 HOT ELECTRON CURRENT INDUCED BY SURFACE REACTIONS 5.12 SUMMARY AND CONCEPTS 5.13 PROBLEMS 6 SURFACE CHEMICAL BOND 6.1 INTRODUCTION 6.2 BONDING TRENDS ACROSS THE PERIODIC TABLE 6.3 CLUSTER-LIKE BONDING OF MOLECULAR ADSORBATES 6.4 THE CARBON MONOXIDE CHEMISORPTION BOND 6.5 ADSORBATE-INDUCED RESTRUCTURING AND THE FLEXIBILITY OF SURFACES 6.6 THERMAL ACTIVATION OF BOND BREAKING 6.7 SURFACE-STRUCTURE SENSITIVITY OF BOND BREAKING 6.8 EFFECTS OF ADSORBATE–ADSORBATE INTERACTION 6.9 WEAK SURFACE BONDS 6.10 SUMMARY AND CONCEPTS 6.11 PROBLEMS 7 MECHANICAL PROPERTIES OF SURFACES 7.1 INTRODUCTION 7.2 BASIC CONCEPTS: ELASTIC MODULUS, YIELD STRENGTH, AND TENSILE STRENGTH 7.3 UNDERSTANDING SURFACE MECHANICAL PROPERTIES AT THE MOLECULAR LEVEL 7.4 ATOMIC FORCE MICROSCOPE 7.5 ELASTIC MECHANICAL PROPERTIES OF SURFACES 7.6 HARDNESS AND YIELD STRENGTH OF SURFACES AT THE NANOMETER SCALE 7.7 NANOTRIBOLOGY 7.8 SINGLE BOND STUDIES 7.9 DIAMOND 7.10 SUMMARY AND CONCEPTS 7.11 PROBLEMS 8 POLYMER SURFACES AND BIOINTERFACES 8.1 INTRODUCTION 8.2 THE EFFECTS OF POLYMER BULK PROPERTIES ON SURFACE PROPERTIES 8.3 SURFACE SEGREGATION ON POLYMER SURFACES 8.4 SURFACE STRUCTURAL RESPONSE TO ENVIRONMENTAL CHANGES 8.5 BIOINTERFACES 8.6 PROTEIN–SURFACE INTERACTIONS 8.7 POLYMER SURFACE CONFORMATION EFFECTS ON PROTEIN ADSORPTION 8.8 ORIENTATION AND CONFORMATION OF ADSORBED BIOMOLECULES 8.9 SUMMARY AND CONCEPTS 8.10 PROBLEMS 9 CATALYSIS BY SURFACES 9.1 INTRODUCTION 9.2 CATALYTIC ACTION 9.3 CATALYST PREPARATION, DEACTIVATION, AND REGENERATION 9.4 TECHNIQUES TO CHARACTERIZE CATALYST SURFACE AND STUDY THE REACTIVITY OF CATALYSTS 9.5 METAL CATALYSIS 9.6 CASE HISTORIES OF SURFACE CATALYSIS 9.7 SELECTIVITY IN MULTIPATH HETEROGENEOUS CATALYTIC REACTIONS 9.8 SUMMARY AND CONCEPTS 9.9 PROBLEMS |
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