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FN Thomson Reuters Web of Scienceâ„?VR 1.0
PT J
AU Liu, Ruihui
   Gao, Nansha
   Zhen, Feng
   Zhang, Yuyan
   Mei, Lin
   Zeng, Xiaowei
TI Doping effect of Al2O3 and CeO2 on Fe2O3 support for gold catalyst in CO
   oxidation at low-temperature
SO CHEMICAL ENGINEERING JOURNAL
VL 225
BP 245
EP 253
DI 10.1016/j.cej.2013.03.118
PD JUN 1 2013
PY 2013
AB Al2O3/CeO2 doped Fe2O3 support was synthesized by co-precipitation
   method, based on which gold was loaded by deposition-precipitation. Both
   the catalytic activity and thermal stability of the gold catalyst were
   enhanced significantly by Al2O3/CeO2 doping. The catalyst loaded with
   1.0% Au and calcined at 180 degrees C converted CO completely at -8.9
   degrees C, while the sample modified by Al2O3/CeO2 showed a 100% CO
   conversion at -20.1 degrees C. Characterization techniques, such as N-2
   adsorption-desorption, X-ray diffraction (XRD), transmission electron
   microscopic (TEM), thermogravimetry-differential scanning calorimeter
   (TG-DSC) and CO2 temperature programmed desorption (CO2-TPD) were
   employed to investigate the structure and surface morphology of the
   catalysts. Al2O3/CeO2 doping retarded the mesoporous structures of the
   catalysts from collapse during the calcination at high temperature,
   which thus maintained higher specific surface area and lower pore size.
   After being calcined at 500 degrees C, the average diameter of the gold
   particles in Au/Fe2O3 was 7.0 nm and the sizes of support grains ranged
   from 50 to 100 nm. However, the average diameter of the gold particles
   in Au/Al2O3/CeO2/Fe2O3 was only 5.1 nm and the sizes of support grains
   ranged from 10 to 30 nm. Gold loaded on the Fe2O3 support by the doping
   of Al2O3/CeO2 have better catalytic activity for CO oxidation. Crown
   Copyright (c) 2013 Published by Elsevier B.V. All rights reserved.
RI Zeng, Xiaowei/A-6506-2015
TC 6
ZB 1
Z8 1
ZS 0
Z9 7
SN 1385-8947
UT WOS:000321313800029
ER

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Ñо¿·½Ïò:Engineering
Web of Science Àà±ð:Engineering, Environmental; Engineering, Chemical
ÎÄÏ×ÐÅÏ¢
ÎÄÏ×ÀàÐÍ:Article
ÓïÖÖ:English
Èë²ØºÅ: WOS:000321313800029
ISSN: 1385-8947
eISSN: 1873-3212
ÆÚ¿¯ÐÅÏ¢
Impact Factor (Ó°ÏìÒò×Ó): Journal Citation Reports®
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Web of Science ºËÐĺϼ¯ÖÐµÄ "ÒýÓõIJο¼ÎÄÏ×": 38
Web of Science ºËÐĺϼ¯ÖÐµÄ "±»ÒýƵ´Î": 5
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