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【奖励】本帖被评价95次，作者nowitzki_ci增加金币 75.6 个

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[资源] Nano Today最新综述：用作纳米反应器的空心纳米粒子的功能化

本综述全面的介绍了中空内心的纳米粒子的制备，中空内心的功能化，纳米反应器的催化反应，限制合成的金属纳米晶。对空心纳米粒子的功能化进行了很好的总结。

Functionalization of hollow nanoparticles for nanoreactor applications 共37页引文253篇
Jihwan Lee, Soo Min Kim, In Su Lee
Department of Chemistry, Pohang University of Science and Technology (POSTECH), Gyeongbuk 790-784, Republic of Korea

Highlights
•Interior-functionalized hollow nanoparticles are promising candidates for nanoreactor.
•Selective interior-functionalization is vital for fabricating hollow nanoreactor.
•Effective functionalization strategies have been suggested to incorporate catalysts.
•Hollow nanoreactors have exhibited superior catalytic performance in various reactions.
•Hollow nanoreactor have recently been employed for templating nanocrystal syntheses.

Summary
The hollow nanoparticles, which contain catalytic species inside the cavity enclosed by a porous nanoshell, are considered an ideal framework for the nanoreactor that efficiently catalyzes the transformation of the selectively transferred substrate molecules with little loss of activity and surface area of entrapped catalysts even in harsh reaction conditions or during the recycling process. In the performance of the hollow nanoreactor, the selectively functionalized interior cavity is the most vital component which allows chemical reactions to occur within the confines of the protected cavity. Therefore, selective and differential functionalization of the internal space of the hollow nanoshell is the important and challenging topic which is demanded for fully exploiting the potential of the hollow nanoparticle in the nanoreactor application. In this context, this review paper intends to make a survey on the synthetic strategies of functionalizing the interior cavity of the hollow nanoparticles and their employment as nanoreator systems which catalyze the chemical reactions and template the growth of nanocrystals.

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