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nowitzki_ci

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[资源] Angew. Chem. Int. Ed.最新综述：化学前瞻

本综述重点介绍了从分子到超分子化学的背景知识，其本质上的动力学反应控制等，失平衡态，其动力学网络，其动力学材料等，对超分子化学做了很好的总结。
Perspectives in Chemistry—Aspects of Adaptive Chemistry and Materials
Jean-Marie Lehn
Chemistry, pure and applied, is a science and an industry. By its power over the expressions of matter, it also displays the creativity of art. It has expanded from molecular to supramolecular chemistry and then,by way of constitutional dynamic chemistry, towards adaptive chemistry. Constitutional dynamics allow for adaptation, through component exchange and selection in response to physical stimuli (e.g.light, photoselection), to chemical effectors (e.g. metal ions, metalloselection) or to environmental effects (e.g. phase change) in equilibrium or out-of-equilibrium conditions, towards the generation of the best-adapted/fittest constituent(s) in a dynamic set. Such dynamic systems can be represented by two-dimensional or three-dimensional dynamic networks that define the agonistic and antagonistic relationships between the different constituents linked through component exchange. The introduction of constitutional dynamics into materials science opens perspectives towards adaptive materials and technologies, presenting attractive behavioral features (such as self-healing). In particular, dynamic polymers may undergo modification of their properties (mechanical, optical, etc.) through component exchange and recombination in response to physical or chemical agents. Constitutional adaptive materials open towards a systems materials science and offer numerous opportunities for soft-matter technologies.

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