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1楼2015-01-22 22:59:22

xhtangxh

木虫 (著名写手)

有木有虫

应助: 773 (博后)
金币: 17832.4
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帖子: 2676
在线: 599.3小时
虫号: 428580
注册: 2007-08-04
专业: 催化化学

【答案】应助回帖

感谢参与，应助指数 +1

自己作图吧，好多种呢。

Card Information
Names: Zirconium Nitride
Formula: Zr N
PDF Number: 31-1493
Quality: star
Subfiles: inorganic alloy

Cell and Symmetry Information
System: cubic Space Group: Fm-3m (no. 225)
a: 4.574
Density (Dx): 7.310 Z: 4

Instrument Information
Radiation: CuKa1 Wavelength: 1.54051
Instrument(d): Guinier Standard: Ge
Instrument(I): diffractometer I type: unknown

Literature References
General: Christensen, A. Acta Chem. Scand., Ser. A 29 563 (1975)
Unit Cell: Christensen, A. J. Cryst. Growth 33 99 (1976)

Peak Data
PeakList
   h    k    l    d    I
   1    1    1 2.6410    25
   2    0    0 2.2870    100
   2    2    0 1.6170    15
   3    1    1 1.3790    14
   2    2    2 1.3210    4

» 本帖已获得的红花（最新10朵）

2楼2015-01-23 10:00:47

xhtangxh

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应助: 773 (博后)
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在线: 599.3小时
虫号: 428580
注册: 2007-08-04
专业: 催化化学

【答案】应助回帖

Card Information
Names: alpha-Zirconium Nitride
Formula: Zr N0.28
PDF Number: 40-1275
Quality: indexed
Subfiles: inorganic alloy

Cell and Symmetry Information
System: hexagonal Space Group: P63/mmc  (no. 194)
a: 3.2220 c: 5.1755
Z: 2

Instrument Information
Radiation: CuKa1 Wavelength: 1.54056
Instrument(d): diffractometer Standard: Si
Instrument(I): diffractometer I type: unknown

Comments and Additional Information
Preparation: Arc melting of ZrN/Zr mixtures and annealing at 1400 K.
General: Lattice parameters depend on composition.
General: Composition near nitrogen-rich phase boundary.

Literature References
General: Lengauer, W., Technische Universitat Wien,Vienna, Austria. Private Communication          (1988)

Peak Data
PeakList
   h    k    l    d    I
   1    0    0 2.7900    20
   0    0    2 2.5880    24
   1    0    1 2.4560    100
   1    0    2 1.8970    18
   1    1    0 1.6110    19
   1    0    3 1.4670    20
   2    0    0 1.3950    2
   1    1    2 1.3680    19
   2    0    1 1.3470    15
   0    0    4 1.2940    3
   2    0    2 1.2280    4
   1    0    4 1.1740    3
   2    0    3 1.0850    8
   2    1    0 1.0550    2
   2    1    1 1.0330    14
   1    1    4 1.0090    10
   2    1    2 0.9767    5
   1    0    5 0.9705    7
   2    0    4 0.9487    2
   3    0    0 0.9301    5
   2    1    3 0.8998    14
   3    0    2 0.8753    10
   0    0    6 0.8626    2
   2    0    5 0.8313    10
   1    0    6 0.8241    4
   2    1    4 0.8175    6
   2    2    0 0.8055    9
   3    1    0 0.7739    11

» 本帖已获得的红花（最新10朵）

3楼2015-01-23 10:04:35

xhtangxh

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应助: 773 (博后)
金币: 17832.4
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Card Information
Names: Zirconium Nitride
Formula: Zr3 N4
PDF Number: 51-646
Quality: star
Subfiles: inorganic alloy

Cell and Symmetry Information
System: orthorhombic Space Group: Pnam    (no.  62)
a: 9.7294 b: 10.8175 c: 3.2810
Density (Dx): 6.340 Z: 4

Instrument Information
Radiation: CuKa1 Wavelength: 1.5406    Filter: Ge
Instrument(d): diffractometer Standard: Si
Instrument(I): diffractometer I type: unknown

Comments and Additional Information
Colour: Red brown
Preparation: Prepared by ammonolysis of Zr Cl4.
General: High-temperature X-ray investigations show a decomposition to Zr N and nitrogen gas at 800 C.
General: Reflections with an intensity <1 have been omitted.

Literature References
General: Lerch, M., Univ. of Wurzburg, Germany. Private Communication          (1998)
Powder: Lerch, M., Fuglein, E., Wrba, J. Z. Anorg. Allg. Chem.  622 367 (1996)

Peak Data
PeakList
   h    k    l    d    I
   1    1    0 7.2340    1
   0    2    0 5.4080    1
   2    1    0 4.4360    2
   2    2    0 3.6170    4
   1    3    0 3.3810    11
   0    1    1 3.1390    9
   3    1    0 3.1060    2
   1    1    1 2.9880    6
   2    3    0 2.8970    4
   3    2    0 2.7810    100
   2    0    1 2.7200    37
   0    4    0 2.7040    30
   1    2    1 2.6950    63
   2    1    1 2.6380    18
   1    4    0 2.6050    7
   0    3    1 2.4260    3
   4    1    0 2.3730    6
   1    3    1 2.3550    29
   3    1    1 2.2560    6
   4    2    0 2.2180    10
   2    3    1 2.1720    9
   1    4    1 2.0400    8
   4    3    0 2.0160    2
   2    5    0 1.9770    1
   4    0    1 1.9540    5
   3    3    1 1.9430    3
   4    1    1 1.9230    1
   2    4    1 1.9180    33
   5    1    0 1.9150    3
   3    5    0 1.8000    1
   3    4    1 1.7550    2
   4    3    1 1.7180    2
   2    5    1 1.6930    18
   2    6    0 1.6900    4
   5    1    1 1.6540    12
   0    0    2 1.6400    18
   6    0    0 1.6220    7
   4    5    0 1.6170    4
   5    2    1 1.5990    22
   4    4    1 1.5840    4
   3    6    0 1.5760    12
   1    6    1 1.5590    6
   1    7    0 1.5260    3
   5    3    1 1.5180    9
   2    6    1 1.5030    4

» 本帖已获得的红花（最新10朵）

4楼2015-01-23 10:05:25

xhtangxh

木虫 (著名写手)

有木有虫

应助: 773 (博后)
金币: 17832.4
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【答案】应助回帖

Card Information
Names: alpha-Zirconium Nitride
Formula: Zr2 N
PDF Number: 46-1204
Quality: questionable
Subfiles: inorganic alloy

Cell and Symmetry Information
System: orthorhombic Space Group: Pnnm    (no.  58)
a: 5.634 b: 5.23 c: 3.253
Z: 2

Instrument Information
Radiation: Neut Wavelength: 1.08
Instrument(d): calculated
Instrument(I): diffractometer I type: unknown

Comments and Additional Information
General: D-values calculated using cell parameters given in reference.
Preparation: Prepared by dehydrogenating Zr N0.35 H0.35 at 1150 K in a vacuum oven during continuous pumping for 20 hours.
Peaks: *Not permitted by space group.
General: Material contains a small quantity of a cubic phase.
Analysis: N/Zr ratio is 0.34 indicating supersaturation.
General: Additional heating of the sample resulted in an orthorhombic distortion of a hcp lattice.
Quality: O assigned because of uncertainty in structure, mixture of phases and presence of metastable phase.

Literature References
General: Khidirov, I., Em, V., Karimov, I., Loryan, V. Phys. Met. Metall. 64 174 (1990)

Peak Data
PeakList
   h    k    l    d    I
   1    0    0 5.6340 * 16
   1    0    1 2.8171    5
   2    0    0 2.8170    5
   0    2    0 2.6150    7
   1    1    1 2.4802    100
   2    1    1 1.9723    10
   1    2    1 1.9166    73
   3    1    0 1.7675    2
   1    3    0 1.6654    3
   0    0    2 1.6265    60
   0    3    1 1.5366    9
   1    1    2 1.4973    35
   2    0    2 1.4086    37
   0    4    0 1.3075    8
   3    3    0 1.2777    4
   4    1    1 1.2548    31
   2    2    2 1.2400    31
   3    1    2 1.1968    2
   1    3    2 1.1636    2
   4    3    0 1.0956    14
* - See Peaks comment

» 本帖已获得的红花（最新10朵）

5楼2015-01-23 10:06:24

小石头00

新虫 (正式写手)

应助: 0 (幼儿园)
金币: 1455.5
散金: 211
红花: 1
帖子: 621
在线: 222.7小时
虫号: 3473160
注册: 2014-10-13
专业: 无机合成和制备化学

引用回帖:

2楼: Originally posted by xhtangxh at 2015-01-23 10:00:47
自己作图吧，好多种呢。

Card Information
Names: Zirconium Nitride
Formula: Zr N
PDF Number: 31-1493
Quality: star
Subfiles: inorganic alloy

Cell and Symmetry Information
System: cubic Spac ...

谢谢！！

6楼2015-01-23 18:41:28

小石头00

新虫 (正式写手)

应助: 0 (幼儿园)
金币: 1455.5
散金: 211
红花: 1
帖子: 621
在线: 222.7小时
虫号: 3473160
注册: 2014-10-13
专业: 无机合成和制备化学

引用回帖:

3楼: Originally posted by xhtangxh at 2015-01-23 10:04:35
Card Information
Names: alpha-Zirconium Nitride
Formula: Zr N0.28
PDF Number: 40-1275
Quality: indexed
Subfiles: inorganic alloy

Cell and Symmetry Information
System: hexagonal Space Group: ...

谢谢！！！

7楼2015-01-23 18:41:45

小石头00

新虫 (正式写手)

应助: 0 (幼儿园)
金币: 1455.5
散金: 211
红花: 1
帖子: 621
在线: 222.7小时
虫号: 3473160
注册: 2014-10-13
专业: 无机合成和制备化学

引用回帖:

4楼: Originally posted by xhtangxh at 2015-01-23 10:05:25
Card Information
Names: Zirconium Nitride
Formula: Zr3 N4
PDF Number: 51-646
Quality: star
Subfiles: inorganic alloy

Cell and Symmetry Information
System: orthorhombic Space Group: Pnam ...

谢谢！！！

8楼2015-01-23 18:42:11

小石头00

新虫 (正式写手)

应助: 0 (幼儿园)
金币: 1455.5
散金: 211
红花: 1
帖子: 621
在线: 222.7小时
虫号: 3473160
注册: 2014-10-13
专业: 无机合成和制备化学

引用回帖:

5楼: Originally posted by xhtangxh at 2015-01-23 10:06:24
Card Information
Names: alpha-Zirconium Nitride
Formula: Zr2 N
PDF Number: 46-1204
Quality: questionable
Subfiles: inorganic alloy

Cell and Symmetry Information
System: orthorhombic Space Gr ...

谢谢！！！

9楼2015-01-23 18:42:34