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北京石油化工学院2026年研究生招生接收调剂公告
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慢三儿

木虫 (小有名气)

[交流] 求救:不含模板剂制备zsm-5

请问有没有人不用有机胺模板剂合成zsm-5分子筛的?
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jinchangzi

至尊木虫 (著名写手)

没听说过,期待高人解答
2楼2008-05-28 08:39:56
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feifeichong

铁虫 (小有名气)

不是有无机氨模板剂作的吗?这方面文献挺多的
3楼2008-05-28 11:03:50
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zhangsh04

木虫 (正式写手)

南开大学可以做,
4楼2008-05-28 11:25:48
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慢三儿

木虫 (小有名气)

不用无机氨或有机胺,就是不用模板剂
按照南开大学的那篇专利根本做不出来,不知道是不是唬人的
5楼2008-05-28 12:48:11
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慢三儿

木虫 (小有名气)

WHO CAN TELL ME?
6楼2008-05-28 22:36:28
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dj_king

铁杆木虫 (著名写手)


nxl5096224(金币+1,VIP+0):3Q!
加些沸石晶种,可以不使用模板剂。
引用回帖:
Originally posted by 慢三儿 at 2008-5-28 12:48:
不用无机氨或有机胺,就是不用模板剂
按照南开大学的那篇专利根本做不出来,不知道是不是唬人的

快乐不打折
7楼2008-05-28 23:00:12
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buffaloli

荣誉版主 (知名作家)

文献很多

★ ★
nxl5096224(金币+2,VIP+0):3Q!
Microporous and Mesoporous Materials
Volume 92, Issues 1-3, 20 June 2006, Pages 181-188

Organic-free synthesis of ZSM-5 with narrow crystal size
distribution using two-step temperature process

Shin Dong Kim, Si Hyun Noh, Jun Woo Park, Wha Jung Kim *
Department of Materials Chemistry and Engineering, Konkuk University, 1-Hwa Yang Dong, Kwang Jin Gu, Seoul 143-701, Republic of Korea
Received 3 May 2005; received in revised form 5 January 2006; accepted 10 January 2006

Abstract
The MFI type of highly silica zeolite, ZSM-5 with well-defined crystal morphology was successfully synthesized in the absence of
organic template using two-step temperature process. In this process, the crystallization process was conducted at two different
temperatures by separating the nucleation and crystallization stage; that is, the nucleation stage at higher temperature (190 C) to
accelerate the nucleation followed by the crystallization stage at lower temperature (150 or 165 C) so as to control the crystal size
and size distribution. The effect of nucleation rate on the final crystal size and size distribution adopting higher temperature of the
first stage for nucleation than that of the second stage for crystallization was investigated. The results show that two-step temperature
process could control the crystal size and size distribution of ZSM-5. The result also shows that the time duration at higher temperature
for the acceleration of nucleation strongly affects the crystal size and size distribution. It implies that rapid nucleation at higher
temperature forms large number of nuclei followed by slow crystal growth probably due to the lack of energy at lower temperature. It
is very critical, therefore that the optimum time duration at higher temperature should be chosen to accelerate the nucleation within
initial stage.

[ Last edited by buffaloli on 2008-5-29 at 14:31 ]
8楼2008-05-29 14:18:38
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慢三儿

木虫 (小有名气)

谢谢大家!!
9楼2008-05-29 21:53:25
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zds1301

铁杆木虫 (著名写手)


buffaloli(金币+1,VIP+0):多谢!可否详细一些?
硅铝比范围小, 初试凝胶配比严格!
10楼2008-05-30 10:40:51
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