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[×ÊÔ´] 2014CRCÐÂÊé-²ÄÁϵĺϳɣ¨Combustion for Material Synthesis£©

Combustion for Material Synthesis
2014CRCÐÂÊé-²ÄÁϵĺϳɣ¨Combustion for Material Synthesis£©
×÷ÕߣºAlexander S. Rogachev, Alexander S. Mukasyan
Ò³Êý£º 424 Pages - 25 Color & 145 B/W Illustrations

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Provides insights from world-renowned specialists in the field of combustion synthesis for advanced materials
Summarizes both the classical works and the recent breakthroughs in the field of combustion synthesis of materials, including reactions in different nano-systems
Reviews modern theoretical approaches and advanced in situ experimental methods for and applications of combustion synthesis materials
Analyzes mechanisms of the structural transformations in the unique conditions of the combustion process for a variety of solid¨Csolid and gas¨Csolid systems
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1. Self-propagating High-temperature Synthesis:
History and Present 1
1.1. Discovery 1
1.2. Gasless combustion synthesis 4
1.3. Combustion synthesis with gasification of the reagents 9
1.4. Combustion synthesis in gas¨Csolid systems 11
1.5. Combustion synthesis with a reduction stage: the thermite type
systems and nanothermites 18
1.6. Combustion synthesis with inorganic compounds as precursors 25
1.7. Thermal decomposition of complex compounds 27
1.8. Solution combustion synthesis 32
1.9. Mechanical activation of initial powder mixtures for SHS 34
1.10. Reactive multilayer nanofilms (foils) 37
2. Thermodynamics and Kinetics of SHS 44
2.1. Introduction 44
2.2. Thermodynamics and driving force of SHS processes 45
2.2.1. Thermodynamics of SHS systems 45
2.2.1.1. General principles 45
2.2.1.2. Equilibrium, reversibility, stationary and stability of the
SHS processes and products 54
2.2.1.3. The equilibrium composition of the SHS products and
the adiabatic combustion temperature 59
2.2.1.4. Examples of thermodynamic calculations for SHS systems 65
2.2.2. Thermodynamics of the preheating¨Creaction zone 77
2.2.3. The thermodynamics of the reaction cell 86
2.3. Kinetics of heterogeneous reactions 90
2.3.1. Solid-state reactions 93
2.3.2. Solid¨Cgas reactions 100
2.3.3. Reactions with the liquid phase 115
2.3.4. Reactions with gasification of the initial solid phase reagent 116
2.3.5. Methods of high-temperature kinetics of heterogeneous
reactions 119
3. Theory of Structural Macrokinetics 125
3.1. Introduction: The concept of structural macrokinetics 125
3.2. Macrokinetics of thermal explosion 128

Index
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