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[资源] 2014CRC新书-材料的合成（Combustion for Material Synthesis）

Combustion for Material Synthesis

作者：Alexander S. Rogachev, Alexander S. Mukasyan
页数： 424 Pages - 25 Color & 145 B/W Illustrations

简介：
Provides insights from world-renowned specialists in the field of combustion synthesis for advanced materials
Summarizes both the classical works and the recent breakthroughs in the field of combustion synthesis of materials, including reactions in different nano-systems
Reviews modern theoretical approaches and advanced in situ experimental methods for and applications of combustion synthesis materials
Analyzes mechanisms of the structural transformations in the unique conditions of the combustion process for a variety of solid–solid and gas–solid systems
目录：
1. Self-propagating High-temperature Synthesis:
History and Present 1
1.1. Discovery 1
1.2. Gasless combustion synthesis 4
1.3. Combustion synthesis with gasification of the reagents 9
1.4. Combustion synthesis in gas–solid systems 11
1.5. Combustion synthesis with a reduction stage: the thermite type
systems and nanothermites 18
1.6. Combustion synthesis with inorganic compounds as precursors 25
1.7. Thermal decomposition of complex compounds 27
1.8. Solution combustion synthesis 32
1.9. Mechanical activation of initial powder mixtures for SHS 34
1.10. Reactive multilayer nanofilms (foils) 37
2. Thermodynamics and Kinetics of SHS 44
2.1. Introduction 44
2.2. Thermodynamics and driving force of SHS processes 45
2.2.1. Thermodynamics of SHS systems 45
2.2.1.1. General principles 45
2.2.1.2. Equilibrium, reversibility, stationary and stability of the
SHS processes and products 54
2.2.1.3. The equilibrium composition of the SHS products and
the adiabatic combustion temperature 59
2.2.1.4. Examples of thermodynamic calculations for SHS systems 65
2.2.2. Thermodynamics of the preheating–reaction zone 77
2.2.3. The thermodynamics of the reaction cell 86
2.3. Kinetics of heterogeneous reactions 90
2.3.1. Solid-state reactions 93
2.3.2. Solid–gas reactions 100
2.3.3. Reactions with the liquid phase 115
2.3.4. Reactions with gasification of the initial solid phase reagent 116
2.3.5. Methods of high-temperature kinetics of heterogeneous
reactions 119
3. Theory of Structural Macrokinetics 125
3.1. Introduction: The concept of structural macrokinetics 125
3.2. Macrokinetics of thermal explosion 128

Index

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2014-12-21 09:24:47, 23 M

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