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Li-ion cells are constructed with an excess amount of Li + in the cathode. Since LiCoO has sufficient amount of active material to completely intercalate carbon,  at 3.74 V. This indicates limitations of either Li + de-intercalation from carbon or Li + insertion into the cathodeno peaks are seen during the forward scan. The peak during the reverse scan occurs


however, the characteristic peak and subsequent relaxation in current, due to diffusion limited processes, which is seen in the reverse scan( discharge ), is absentnduring the forward sweep. This indicates that there are no limitations in inserting Li + into carbon and also in removing it from the cathode


请教一下,我在一篇文献中看到两句话,不是很理解,希望能够找到高人解释一下。其中第一句话对应CV1,第二句话对应CV2。我很不明白他们是怎么得到那样的结论的

循环伏安
cv1.jpg


循环伏安-1
cv2.jpg
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