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M201175065金虫 (正式写手)
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[求助]
维普求助,多谢 已有1人参与
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| 13C NMR (101 MHz, Pyr) δ 13.05. 14.06, 21.21, 27.41, 29.94, 35, 31. 39. 76, 39.79, 40.05, 41.10, 44.92, 52.78, 56.87, 59.29, 74.98, 107.26, 125.61, 142.20, 150.26, 180.40, |
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【答案】应助回帖
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感谢参与,应助指数 +1
M201175065: 金币+10, ★★★★★最佳答案, 很好 2014-12-24 13:41:36
感谢参与,应助指数 +1
M201175065: 金币+10, ★★★★★最佳答案, 很好 2014-12-24 13:41:36
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查询模式:模糊查询 碳谱数据输入: 按从小到大顺序输入,数字间用英文半角逗号(,)分隔例如: 21.4,30.4,37.4,73.2,73.7,125.6,126.6,139.6,140.2,168.2 13.05,14.06,21.21,27.41,29.94,35.31,39.76,39.79, 40.05,41.10,44.92,52.78,56.87,59.29,74.98,107.26, 125.61,142.20,150.26,180.40 溶剂选项: 全部 CDCl3 CD3CD2OD CD2Cl2 C5D5N C3D7NO CD3SOCD3 C4D8O CD3COOD C4D8O2 D2O CF3COOD CD3OD CD3COCD3 C6D6 CD3CN 查询空值 匹配容差: (数字格式,可自行设定) 相似度: %(相似度>=50%) 查询结果:共查到219个化合物(查询结果仅供参考) -------------------------------------------------------------------------------- 1 . henrilabdane A C20H32O4 相似度:90% Phytochemistry 2008 69 2867-2874 Bis-sesquiterpenes and diterpenes from Chloranthus henryi Chuang-Jun Li, Dong-Ming Zhang, Yong-Ming Luo, Shi-Shan Yu, Yan Li, Yang Lu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 2 . 16-Methyl-12,15-epoxy-8(17),13-labdadien-19-oic acid C20H30O3 相似度:85% Journal of Asian Natural Products Research 2006 8 677-682 Labdane diterpenes from the seeds of Platycladus orientalis X.-Y. REN and Y. YE Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 3 . 12R,15-dihydroxylabda-8(17),13E-dien-19-oic acid C20H32O4 相似度:75% Phytochemistry 2008 69 518-526 Diterpenoids from the pericarp of Platycladus orientalis Ya-Zhou Wang, Chun-Ping Tang, Chang-Qiang Ke, Hans-Christoph Weiss,Ernst-Rudolf Gesing, Yang Ye Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 4 . 12R,15-dihydroxylabda-8(17),13Z-dien-19-oic acid C20H32O4 相似度:75% Phytochemistry 2008 69 518-526 Diterpenoids from the pericarp of Platycladus orientalis Ya-Zhou Wang, Chun-Ping Tang, Chang-Qiang Ke, Hans-Christoph Weiss,Ernst-Rudolf Gesing, Yang Ye Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 5 . 15-hydroxy-12-oxolabda-8(17),13E-dien-19-oic acid C20H30O4 相似度:75% Phytochemistry 2008 69 518-526 Diterpenoids from the pericarp of Platycladus orientalis Ya-Zhou Wang, Chun-Ping Tang, Chang-Qiang Ke, Hans-Christoph Weiss,Ernst-Rudolf Gesing, Yang Ye Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 6 . 12R,15-dihydroxy-8(17),13E-labdadien-19-oic acid 相似度:75% Tetrahedron Letters 2009 50 4185-4187 A novel sulfur-containing diterpenoid from Fritillaria anhuiensis Qing-Yao Shou, Qing Tan, Zheng-Wu Shen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 7 . henrilabdane B C20H32O4 相似度:70% Phytochemistry 2008 69 2867-2874 Bis-sesquiterpenes and diterpenes from Chloranthus henryi Chuang-Jun Li, Dong-Ming Zhang, Yong-Ming Luo, Shi-Shan Yu, Yan Li, Yang Lu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 8 . henrilabdane C C20H30O4 相似度:70% Phytochemistry 2008 69 2867-2874 Bis-sesquiterpenes and diterpenes from Chloranthus henryi Chuang-Jun Li, Dong-Ming Zhang, Yong-Ming Luo, Shi-Shan Yu, Yan Li, Yang Lu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 9 . acrostalic acid 相似度:70% Helvetica Chimica Acta 2009 92 1118-1125 Labdane and Tetranorlabdane Diterpenoids from Botryosphaeria sp. MHF, an Endophytic fungus of Maytenus hookeri Lin Yuan, Pei-Ji Zhao, Juan Ma, Chun-Hua Lu, Yue-Mao Shen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 10 . 12,15-dihydroxylabda-8(17),13Z-dien-19-oic acid C20H30O3 相似度:70% Phytochemistry 1993 34 1581-1584 Diterpenes from the bark of Juniperus chinensis Fang Jim-Min, Sou Yi-Chien, Chiu Yu-Hung, Cheng Yu-Shia Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 11 . 15,16-Epoxy-12-hydroxy-8(17),13(16),14-labdatrien-19-oic acid C20H28O4 相似度:70% Phytochemical Analysis 2006 17 32-35 Labdane Diterpenes from Juniperus communis L. Berries Anne Marie Martin, Emerson Ferreira Queiroz, Andrew Marston and Kurt Hostettmann Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 12 . 13ξ,14β-dihydroxy-8(17)-labdaen-(15→16)-lactone-19-oicacid C20H30O6 相似度:70% Journal of Asian Natural Products Research 2014 16 555-564 Five new terpenoids from the rhizomes of Isodon adenantha Xing-Li Zhou, Chao-Jiang Xiao, La-Bin Wu, Bo Huang, Xiang Dong & Bei Jiang Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 13 . 16-hydroxy-8(17),13-ent-labdadien-15,16-olid-19-oic acid C20H28O5 相似度:65% Phytochemistry 2003 1309-1317 ent-Labdane diterpenes from the aquatic plant Potamogeton pectinatus Patrice Waridel, Jean-Luc Wolfender, Jean-Bernard Lachavanne, Kurt Hostettmann Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 14 . labda-8(17),13(Z)-diene-15,19-dioic acid C20H30O4 相似度:65% Journal of Natural Products 1998 61 51-56 In Vitro Biotransformations of Isocupressic Acid by Cow Rumen Preparations:Formation of Agathic and Dihydroagathic Acids Shwu-Jiuan Lin, Robert E. Short, Stephen P. Ford, Elaine E. Grings, and John P. N. Rosazza Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 15 . (12R)-labda-8(17),13E-diene-12,15,19-triol C20H34O3 相似度:65% Planta Medica 2009 75 1344-1348 Terpenoids from Roots of Chloranthus henryi Xianwen Gan, LeiMa, Qigang Chen, Qiuqun Chen, Qiang Yu, Lihong Hu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 16 . Botryosphaerin E C20H32O5 相似度:65% Helvetica Chimica Acta 2009 92 1118-1125 Labdane and Tetranorlabdane Diterpenoids from Botryosphaeria sp. MHF, an Endophytic fungus of Maytenus hookeri Lin Yuan, Pei-Ji Zhao, Juan Ma, Chun-Hua Lu, Yue-Mao Shen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 17 . ((E)-Labda-8(17),12,14-trien-19-oic acid C20H30O2 相似度:65% Monatshefte für Chemie 2000 131 401-408 A Diterpene, a Flavonol Glycoside, and a Phytosterol Glycoside from Securidaca longipedunculata and Entada abyssinica Asfaw Debella, Olaf Kunert, Martin G. Schmid, GuÈnter Michl, Franz Bucar, Dawit Abebe, and Ernst Haslinger Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 18 . 7β-hydroxyisocupressic acid C21H34O4 相似度:60% Journal of Natural Products 1998 61 922-926 Microbial Transformations of Isocupressic Acid Shwu-Jiuan Lin and John P. N. Rosazza Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 19 . 12,15-epoxy-5αH,9βH-labda-8(17),13-dien-19-oic acid C20H30O3 相似度:60% Planta Medica 2006 72 1334-1338 Bioactive Terpenes from the Roots of Chloranthus henryi Bin Wu , Shan He , Xiao-dan Wu , Yuan-jiang Pan Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 20 . 12(R)-12,15-dihydroxylabda-8(17),13E-dien-19-oic acid 相似度:60% Planta Medica 2009 75 1344-1348 Terpenoids from Roots of Chloranthus henryi Xianwen Gan, LeiMa, Qigang Chen, Qiuqun Chen, Qiang Yu, Lihong Hu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 21 . 11-hydroxyldrim-8,12-en-14-oic acid C15H24O3 相似度:60% Planta Medica 2009 75 1344-1348 Terpenoids from Roots of Chloranthus henryi Xianwen Gan, LeiMa, Qigang Chen, Qiuqun Chen, Qiang Yu, Lihong Hu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 22 . ent-13,17-dihydroxy-kaur-15-en-19-oic acid 相似度:60% Phytochemistry 1992 31 1553-1559 Minor diterpene glycosides from sweet leaves of Rubus suavissimus Kazuhiro Ohtani, Yoko Aikawa, Ryoji Kasai, Wen-Hua Chou, Kazuo Yamasaki, Osamu Tanaka Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 23 . 7 α-Hydroxy-(-)-pimara-8(14),15-dien-19-oic acid 相似度:60% Archives of Pharmacal Research 2005 28 28-33 Inhibitory Constituents against Cyclooxygenases fromAralia cordata Thunb Nguyen Hai Dang, XinFeng Zhang, MingShan Zheng, Kun Ho Son and Hyeun Wook Chang, et al. Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 24 . (8R)-15,16-epoxy-8,17-dihydroxy-13(16),14-labdadien-18-oic acid C20H30O5 相似度:60% Russian Journal of Organic Chemistry 2006 42 36-41 Synthetic transformations of higher terpenoids: XII. Transformation of lambertianic acid into 14,16-epoxyabietane diterpenoids S. V. Chernov, E. E. Shul’ts, M. M. Shakirov and G. A. Tolstikov Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 25 . compound 25 相似度:60% Canadian Journal of Chemistry 1979 57 1550-1556 13C nuclear magnetic resonance studies. 85. 13C spectra of several ring-contracted and -expanded steroids Vinod Dave, J. B. Stothers Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 26 . Isostevic acid 相似度:60% Phytochemistry 2012 75 90-98 Oxygenated compounds from the bioconversion of isostevic acid and their inhibition of TNF-α and COX-2 expressions in LPS-stimulated RAW 264.7 cells Li-Ming Yang, Shwu-Fen Chang, Wen-Kuang Lin, Bo-Hon Chou, Li-Hsuan Wang, Pan-Chun Liu, Shwu-Jiuan Lin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 27 . compound 3 C20H30O4 相似度:60% Phytochemistry 2012 75 90-98 Oxygenated compounds from the bioconversion of isostevic acid and their inhibition of TNF-α and COX-2 expressions in LPS-stimulated RAW 264.7 cells Li-Ming Yang, Shwu-Fen Chang, Wen-Kuang Lin, Bo-Hon Chou, Li-Hsuan Wang, Pan-Chun Liu, Shwu-Jiuan Lin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 28 . Platencin SL1 C20H30O4 相似度:60% Journal of Natural Products 2012 75 2158-2167 Expression of the Platencin Biosynthetic Gene Cluster in Heterologous Hosts Yielding New Platencin Congeners Michael J. Smanski, Jeffrey Casper, Ryan M. Peterson, Zhiguo Yu, Scott R. Rajski, and Ben Shen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 29 . Platencin SL2 C18H28O3 相似度:60% Journal of Natural Products 2012 75 2158-2167 Expression of the Platencin Biosynthetic Gene Cluster in Heterologous Hosts Yielding New Platencin Congeners Michael J. Smanski, Jeffrey Casper, Ryan M. Peterson, Zhiguo Yu, Scott R. Rajski, and Ben Shen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 30 . 20-hydroxy-pregna-1-en-3-one 相似度:57.1% Drugs & Clinic 2014 29 11-15 Chemical constituents in ethyl acetate fraction from Scleronephthya sp. YU Yang, LIU Zhen, LIN Wen-han, JI Yu-bin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 31 . 14(RS),15-dihydroxy-8(17),12(E)-labdadien-19-oic-acid C20H32O4 相似度:56.5% Biochemical Systematics and Ecology 2012 45 16-19 Chemical constituents from Fritillaria anhuiensis Qingyao Shou, Hans Wohlmuth, Xiaoxiang He, Lei Liu, Zhengwu Shen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 32 . 14-methoxy-15,16-dinor-5αH,9αH-labda-13(E),8(17)-dien-12 -one C19H30O2 相似度:55% Planta Medica 2006 72 1334-1338 Bioactive Terpenes from the Roots of Chloranthus henryi Bin Wu , Shan He , Xiao-dan Wu , Yuan-jiang Pan Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 33 . 12β,16α,17,19-tetrahydroxy-ent-kaurane C20H34O4 相似度:55% Chemical & Pharmaceutical Bulletin 1983 31 3865-3871 Chemical and Chemotaxonomical Studies on Filices. XLIII. Chemical Studies on the Constituents of Lindsaea javanensis BL., L. japonica (BAK.) DIELS and Tapeinidium pinnatum (CAV.) C. CHR. TOSHIKO SATAKE,TAKAO MURAKAMI,YASUHISA SAIKI and CHIUMING CHEN Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 34 . 14(R),15-Dihydroxy-8(17),12(E)–labdadien-19-oic acid C20H32O4 相似度:55% Journal of Asian Natural Products Research 2006 8 677-682 Labdane diterpenes from the seeds of Platycladus orientalis X.-Y. REN and Y. YE Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 35 . 15,16-Dihydroxy-8(17),13(E)–labdadien-19-oic acid C20H32O4 相似度:55% Journal of Asian Natural Products Research 2006 8 677-682 Labdane diterpenes from the seeds of Platycladus orientalis X.-Y. REN and Y. YE Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 36 . incarvine D 相似度:55% China Journal of Chinese Materia Medica 2009 34 1672-1675 Chemical constituents from roots of Incarvillea mairei HUANG Zhengsheng, ZHANG Weidong, LIN Sheng, LIU Chunmei, HUANG Dasen, SONG Taifa, LU Longhai, PEI Yuehu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 37 . 6β,11α,17β,-Trihydroxy-17α-methylandrost-4-en-3-one C20H30O4 相似度:55% Phytochemistry 1996 42 411-415 The hydroxylation of testosterone and some relatives by Cephalosporium aphidicola James R. Hanson, Habib Nasir, Aslam Parvez Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 38 . compound 6m 相似度:55% Journal of Natural Products 1984 Vol 47 592-599 Cmr Spectroscopy of Labdanic Diterpenes and Related Substances Josette Bastard, Do Khac Duc, Marcel Fetizon, Malcolm J. Francis, Peter K. Grant, Rex T. Weavers, Chikara Kaneko, G. Vernon Baddeley, Jean-Marie Bernassau, Ivor R. Burfitt, Peter M. Wovkulich, Ernest Wenkert Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 39 . 12,15-epoxy-8(17),13-labdadien-19-ol C20H32O2 相似度:55% Acta Pharmaceutica Sinica 2007 Vol 42 58-60 A new diterpenoid from Fritillaria anhuiensis KANG Lu; ZHOU Jian-xia; SHEN Zheng-wu Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 40 . 7β,15-dihydroxy-labd-8(17)-en C20H36O2 相似度:55% Phytochemistry 1991 30 2785-2787 Acetylenes and labdanes from Baccharis pedunculata J. Jakupovic, A. Schuster, D.C. Wasshausen Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 41 . Pterisolic Acid B C20H26O4 相似度:55% Chemical & Pharmaceutical Bulletin 2011 59(4) 484-487 Pterisolic Acids A—F, New ent-Kaurane Diterpenoids from the Fern Pteris semipinnata Fei WANG, Ya-Ju LI, Fu-Cai REN, Guo-Zhu WEI, and Ji-Kai LIU Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 42 . ent-19-nor-atidan-4(18)-en-16α-ol 相似度:55% Phytochemistry 1988 27 3205-3208 Diterpenes from the fruits of Xylopia aromatica Miguel P. L. Moraes,Nidia F. Roque Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 43 . 16-hydroxy-labda-8(17),13-diene-15,19-dioic acid butenolide 相似度:55% Phytochemistry 1989 28 1173-1175 Terpenoids from leaves of Calocedrus formosana Jim-min Fang,Kuo-chio Hsu,Yu-shia Cheng Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 44 . 6β-hydroxy-7-oxo-ent-atis-16-en-19-oic acid C20H28O4 相似度:55% Phytochemistry 2010 71 1313-1321 Biotransformation of 7α-hydroxy- and 7-oxo-ent-atis-16-ene derivatives by the fungus Gibberella fujikuroi Braulio M. Fraga, Pedro Gonzalez, Victoria Gonzalez-Vallejo, Ricardo Guillermo, Luz N. Diaz Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 45 . Ent-12α,16β,17-trihydroxy-kauran-19-oic acid C20H32O5 相似度:55% Natural Product Research 2010 24 905-914 Biotransformation of ent-kaur-16-en-19-oic acid by Psilocybe cubensis Jaraslak Pechwang; Prakitsin Sihanonth; Surachai Pornpakakul; Nongnuj Muangsin; Jittra Piapukiew; Alisa Vangnai; Narongsak Chaichit; Siriporn Chuchawankul; Amorn Petsom Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 46 . compound 2 相似度:55% Pharmazie 2000 55 704-706 Analgetic properties of glycosyl diclofenac derivatives J. Borowiecka - W. Pakulska - E. Czarnecka Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 47 . 7α-Hydroxy-ent-pimara-8(14),15-diene-19-oic acid 相似度:55% Archives of Pharmacal Research 2009 32 1399-1408 Cholinesterase and BACE1 inhibitory diterpenoids from Aralia cordata Hyun Ah Jung, Eun Ju Lee, Ju Sun Kim, Sam Sik Kang and Je-Hyun Lee, et al. Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 48 . 8(17),13(E)-labdadien-15,19-dioic acid 相似度:55% Natural Product Research and Development 2008 20 1000-1004 Chemical Constituents from Amoora ouangtliensis and A.stellato-squamosa YANG Shu-min;LIU Xi-kui*; WU Da-gang; ZHU Da-yuan Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 49 . compound 19a C20H31NO3 相似度:55% Bioorganic & Medicinal Chemistry 2009 17 1464-1473 Stereoselective synthesis of bioactive isosteviol derivatives as α-glucosidase inhibitors Ya Wu, Jing-Hua Yang, Gui-Fu Dai, Cong-Jun Liu, Guo-Qiang Tian, Wen-Yan Ma, Jing-Chao Tao Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 50 . ent-8β-cyanom-ethyl-13-methyl-12-podocarpen-19-oic acid C20H29NO2 相似度:55% Bioorganic & Medicinal Chemistry 2009 17 6348-6353 Microbial transformation of isosteviol oxime and the inhibitory effects on NF-κB and AP-1 activation in LPS-stimulated macrophages Shwu-Fen Chang, Bo-Hon Chou, Li-Ming Yang, Feng-Lin Hsu, Wen-Kuang Lin, Yi Ho, Shwu-Jiuan Lin Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 51 . 2α-hydroxy-3-isobutyl-1,2,3,4,6,7-hexahydro-11bH-benzo[a]quinolizine 相似度:55% Journal of Medicinal Chemistry 1996 39 191-196 In Vitro and in Vivo Studies of Benzisoquinoline Ligands for the Brain Synaptic Vesicle Monoamine Transporter Lihsueh C. Lee, Thierry Vander Borght, Phillip S. Sherman, Kirk A. Frey, and Michael R. Kilbourn Structure 13C NMR 碳谱模拟图 -------------------------------------------------------------------------------- 52 . ceriponol I C16H26O5 相似度:55% Phytochemistry 2013 95 360-367 Ceriponols A-K, tremulane sesquitepenes from Ceriporia lacerate HS-ZJUT-C13A, a fungal endophyte of Huperzia serrata You-Min Ying, Wei-Guang Shan, Li-Wen Zhang, Zha-Jun Zhan Structure 13C NMR 碳谱模拟图 |

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