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银虫 (小有名气)

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专业: 无机非金属类光电信息与功

[求助] why the cell impedance is equivalent to the electrode impedance 已有1人参与

投了篇文章，我用纽扣电池在AUto -Lab 上做的EIS，审稿意见下来了；
然后我用拟合拟合的电路，拟合出对应的Rct Rf 等值，看到这个回复很迷惑啊，我觉得这块好像没问题吧。
the impedance apparently was measured in a two-electrode arrangement yielding cell and not electrode impedances, whereas the equivalent circuit and all discussion implies, that electrode impedances were measured and evaluated. This is a fundamental contradiction, it is unacceptable and basically wrong. Either you have to explain why the cell impedance is equivalent to the electrode impedance - hard to believe - or your better remove this section.

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