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[资源] 2013年新著关于手性的好书：Differentiation of Enantiomers

Differentiation of Enantiomers I
ISSN 0340-1022 ISSN 1436-5049 (electronic)
ISBN 978-3-319-03238-2 ISBN 978-3-319-03239-9 (eBook)
DOI 10.1007/978-3-319-03239-9
Springer Heidelberg New York Dordrecht London
In the wake of enantioselective syntheses and chiral technologies, efﬁcient analytical methods for the differentiation of enantiomers have become essential. Earlier compendia in this area need updating due to important recent advances made in the realm of enantiomeric differentiation. Precise analytical tools for the determination of enantiomeric proportions are important in many contemporary ﬁelds associated with various aspects of chirality. The distribution of enantioselective methods for the determination of enantiomeric proportions utilized in 319 published articles of Tetrahedron Asymmetry 2003, i.e., polarimetry , gas chromatography (GC), high performance liquid chromatography (HPLC), and nuclear magnetic resonance spectroscopy (NMR),has been compiled previously.
These two volumes of Topics in Current Chemistry review various modern methods and techniques of enantiomeric differentiation. Individual chapters have been written by pioneers in the ﬁeld and emerge from renowned laboratories which have contributed signiﬁcantly to recent research. In each chapter emphasis has been given to an extended reference format including the titles of related original work which will enable readers to appreciate and consult the important secondary literature.
The ﬁrst volume begins with an introduction to historic and fundamental aspects of chirality followed by recommendations on how to quantify mixtures of stereoisomers. Enantiomeric differentiation by chiral liquid chromatography utilizing supramolecular chiral recognition systems and various chiroptic approaches is described. Enantiomeric differentiation by gas chromatography and capillary elec trophoresis concludes the ﬁrst volume. The second volume begins with enantiomeric differentiation by NMR spectroscopy and sensor devices followed by chiral recognition phenomena in supramolecular chemistry, chromatographic studies of stereolabile interconverting enantiomers, and anisotropy spectroscopy as a novel extension of circular dichroism. The second volume is concluded with the self-disproportionation of enantiomers due to nonlinear effects.
We hope that these volumes on the differentiation of enantiomers will provide inspiration and impetus to further advances in the ever-growing area of stereochemistry. The editor is grateful to all the colleagues who have helped to create this survey on modern tools for the differentiation of enantiomers.
Contents
Molecular Chirality: Language, History, and Signiﬁcance ................. 1
Joseph Gal
Terms for the Quantitation of a Mixture of Stereoisomers ................ 21
Volker Schurig
Enantiomeric Differentiation by Synthetic Helical Polymers ............. 41
Eiji Yashima, Hiroki Iida, and Yoshio Okamoto
Chiral Supramolecular Selectors for Enantiomer Differentiation in
Liquid Chromatography ...................................................... 73
Alessia Ciogli, Dorina Kotoni, Francesco Gasparrini, Marco Pierini,
and Claudio Villani
Chiroptical Detectors for the Study of Unusual Phenomena in Chiral
Chromatography ............................................................. 107
Nicolas Vanthuyne and Christian Roussel
Salient Features of Enantioselective Gas Chromatography:
The Enantiomeric Differentiation of Chiral Inhalation Anesthetics
as a Representative Methodological Case in Point ........................ 153
Volker Schurig
Differentiation of Enantiomers by Capillary Electrophoresis ............ 209
Gerhard K.E. Scriba
Index .......................................................................... 277

Differentiation of Enantiomers II

Contents
Chiral Derivatizing Agents, Macrocycles, Metal Complexes,
and Liquid Crystals for Enantiomer Differentiation
in NMR Spectroscopy .......................................................... 1
Thomas J. Wenzel
Chiral NMR Solvating Additives for Differentiation of Enantiomers .... 69
Gloria Uccello-Barretta and Federica Balzano
Chiral Sensor Devices for Differentiation of Enantiomers ............... 133
Kyriaki Manoli, Maria Magliulo, and Luisa Torsi
Enantiopure Supramolecular Cages: Synthesis and Chiral Recognition
Properties ..................................................................... 177
Thierry Brotin, Laure Guy, Alexandre Martinez, and Jean-Pierre Dutasta
Interconversion of Stereochemically Labile Enantiomers
(Enantiomerization) .......................................................... 231
Oliver Trapp
Anisotropy Spectra for Enantiomeric Differentiation of Biomolecular
Building Blocks ............................................................... 271
A.C. Evans, C. Meinert, J.H. Bredeho¨ft, C. Giri, N.C. Jones, S.V. Hoffmann,
and U.J. Meierhenrich
Self-disproportionation of Enantiomers of Enantiomerically
Enriched Compounds ........................................................ 301
Alexander E. Sorochinsky and Vadim A. Soloshonok
Index .......................................................................... 341