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| The solid-state PL spectra of the compounds on TLC plates (aluminium TLC plate, Merck, Silica 60 F254) were measured according to the literature procedure. 20 Cyclic voltammetry (CV) measurement was carried out on a Shanghai Chenhua electrochemical workstation CHI660C in a three-electrode cell with a Pt disk counter electrode, a Ag/AgCl reference electrode, and a glassy carbon working electrode. All CV measurements were performed under an inert argon atmo-sphere with supporting electrolyte of 0.1M n-Bu4NClO4 in dichloromethane at scan rate of 100 mV s 1 using ferrocene (Fc) as the standard. The lowest unoccupied molecular orbital/highest occupied molecular orbital (LUMO/HOMO) energy gapsDEg for the compounds were estimated from the absorption edge of the UV-vis absorption spectra |
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