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A new class of compounds containing dicarbazolyl triphenyl-ethylene and triarylamine units was synthesized. The compounds possessed high thermal stability and AIEE properties. The glass transition temperature and 5% weight loss temperature of the tri-substituted compound (3B-TPA) are up to 214.3  C and 516.8 C, respectively. TheTgvalue is the highest ever reported to date for materials with AIE or AIEE properties. The compounds exhibited photo-induced intramolecular charge-transfer proper-ties
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