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| As can be seen, the DEg values decreased with an increase in the number of dicarbazolyl triphenylethylene substituents. Therefore, compounds 3B-TPA and 1B-TPA exhibited the narrowest energy band gap and the widest energy band gap, respectively. HOMO values ranged from 5.12–5.19 eV. The HOMO values also depended on the number of the dicar-bazolyl triphenylethylene substituents: the larger the number, the smaller the HOMO value. However, LUMO values ranged from 2.37–2.38 eV and were very close to each other. |
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2楼2014-11-08 04:13:36