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| The large bathochromic shift combined with the decreasedF might be related to the stabilization of the excited state. This behavior is frequently observed in highly polarized molecules exhibiting enlarged dipoles and charge-transfer characters in their excited states referred to as intramolecular charge-transfers (ICT). 13 Since solvent polarity had little effect on the absorption wavelengths of the compounds, their solvatochromisms might be caused by photo-induced ICT in the excited state, suggesting that the ICT excited state had a larger dipolar moment compared with the ground state, due to substantial charge redistribution. |
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