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Itis well-known that in the condensed phase, the luminescence properties of a given molecular system usually undergo significant variation according to the molecular aggregation state or stacking mode, since intermolecular interactions invariably alter photophysical processes.[2c,3] Therefore, an understanding of and the ability to control the molecular aggregation state and the consequent intermolecular interactions are still very important for the development of piezochromic materials. Herein we report an effective mechanism of piezochromic luminescence on the basis of the molecular aggregation state of 9,10-bis((E)-2-(pyrid-2-yl)vinyl)anthracene (BP2VA). |
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