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| The common structural characteristics of AIE molecules are the strongly twisted skeleton conformations, 14,15 which could hinder solid-state intermolecular close stacking and intense π–π interaction and might result in these materials possessing mechanical stress-dependent stable and metastable solid morphologies that show different optical and optoelectronic properties. However, PFC materials are still at the initial stages of investigation, and the kinds of PFC materials and in-depth understanding of PFC phenomena are limited. Therefore, there is still a great demand on exploitation of new PFC materials and accumulation of knowledge of their structure–property relationships. In this context, the design and synthesis of new PFC materials with comparable molecular structures and the investigation of PFC behaviour are very interesting but scarce. |
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RXMCDM: 金币+1, 多谢应助！ 2014-10-18 01:36:03
yhc0316: 金币+20, 翻译EPI+1 2014-10-19 14:11:22
RXMCDM: 金币+1, 多谢应助！ 2014-10-18 01:36:03
yhc0316: 金币+20, 翻译EPI+1 2014-10-19 14:11:22
| AIE分子的共同结构特点是强烈扭曲的骨架构象【14,15】，这可能阻碍固态分子间紧密的堆叠和强烈的π-π相互作用，使这些材料具有机械应力依赖性稳定和亚稳态固体形态，表现出不同的光学和光电性能。然而，PFC材料仍处于研究的初始阶段，对PFC材料的种类、以及PFC现象的深入了解都很有限。因此，仍然有开发新PFC材料以及对其结构 - 性能关系的知识积累有很大的需求。在这种情况下，设计和合成具有可比较分子结构的新型PFC材料以及研究PFC的性能是非常有趣的，但很少。 |
2楼2014-10-17 21:45:12
