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zhangwei章薇

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Furthermore, FC4 and FC8 solids are molten and then rapidly put into liquid N2, which should afford real amorphous states. It is shown that the quenched solids have thesame emission spectra as the ground or pressed samples (Fig. 6). These  findings indicate that the transformation between the amorphous and crystalline states under
various external stimuli is responsible for the reversible PFC behaviour. Further inspection of the DSC curves of the ground solids reveals that the cold-crystallization temperatures (Tcc) of the ground FCn solids decreases gradually with the length of N-alkyl chains (Fig. 5b and Table 1). Based on the decreased rate of Tcc from FC1 to FC8, the Tcc values of the ground FC10 and FC12 should be at or below room temperature. This implies that changing the length of the N-alkyl chains can significantly affect the Tcc of amorphous FCn solids.
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