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Fig. 6. Comparison of x-ray diffraction in hot face & interface. Fig. 6 presents the XRD peak of main compounds of the hot face and interface.
We may identify that the alumina peak of hot face is relatively low, but the levels of spinel and CA6 peak are high in comparison with the interface.
The differences in formation of spinel and CA6 may bring about mechanical stress between hot face and interface, producing structural spalling.
Additionally, the excessive formation of CA6 in the matrix may cause microcracks4), which frequently results in spalling. Therefore, the ASM (C), in
which the microsilica was increased by 0.7% of microsilica was used to repress the expansion of spinel and CA6.
Fig. 7 shows the photos of hot face that had been applied to steel ladle after 100 heats.
Fig. 7. Photograph of field test of ASM (B & C) after 100heats.
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RXMCDM: 金币+1, 多谢应助! 2014-09-23 19:40:38
英语留级生: 金币+12, 翻译EPI+1, ★★★★★最佳答案, 非常非常感谢 2014-09-25 13:39:02
图6 加热面和交界面上X射线衍射对比
图6展示了加热面和交界面上主要化合物的XRD峰值。我们能确定加热面上的氧化铝峰值相对较低,但对比于交界面上,其尖晶石和CA6峰值很高。由于形成尖晶石和CA6的差异,在加热面和交界面上可能会产生机械应力,导致结构散裂。另外,基体上大量形成的CA6可能会导致微裂纹,从而进一步导致散裂。因此,在ASM (C)中,硅粉增加了0.7%,它是用来抑制尖晶石和CA6的扩展。
图7 展示了100次加热后,应用于钢水包后的加热面照片
图7 100次加热后,ASM (B & C)的现场测试照片。
2楼2014-09-23 16:06:39
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