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04120152

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In recent years organic semiconductors have attracted considerable interest due to th growing potential as active materials in electronic and optoelectronic devices. A long standing paradigm, however. has been seen in their unipolar transport of electrical charges. Thus multi-layer structures comprising different organic materials faith spatially separated electron and hole transport layers inhere used for fabricating efficient organ light-emitting diodes [1]. On the other hand in photovoltaic devices. owing to she exciton diffusion length in organic semiconductors. p- and n-conducting materials need be in close contact which is usually realized by mixing them in one single layer yielding so called bulk-heterojunction structure [2-5]. Recently,such donor-acceptormixtures ha been implemented also in organic field-effect transistors (OFETs).  Ambipolar OFE have been realized faith a variety of material combinations. including polymer fullere blends [6], mixtures of soluble oligomers [7] as well as evaporated molecular hetero-lay structures and mixed layers [8].
Our recent studies in this field have focussed on the combination of hole conducting copper-phthalocyanine (CuPc) with the electron conducting fullerene C60. We have investigated OFETs with various mixing ratios and film preparation conditions and have demonstrated ambipolar inverters with these blends [9]. Using photoelectric spectroscopy, Are have recently determined the occupied electronic levels and the changes upon mixing both materials [10]. in this contribution we will summarize the result and discuss their implications in the context of photovoltaic cells based on combination of CuPc as electron donor and C60 as electron acceptor, respectively. particular eve will demonstrate that differences in the open-circuit voltages of heterolayer cells and bulk-heterojunction devices can be traced back to the electronic structure of the blends.
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04120152

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有几处拼写错误

In recent years organic semiconductors have attracted considerable interest due to their growing potential as active materials in electronic and optoelectronic devices. A long-standing paradigm, however, has been seen  in their unipolar transport of electrical charges. Thus multi-layer structures comprising different organic materials with spatially separated electron and hole transport layers where used for fabricating efficient organic light-emitting diodes [1]. On the other hand in photovoltaic devices, owing to short exciton diffusion length in organic semiconductors, p- and n-conducting materials need to be in close contact which is usually realized by mixing them in one single layer yielding a
so-called bulk-heterojunction structure [2-5]. Recently, such donor-acceptor mixtures have been implemented also in organic field-effect transistors (OFETs). Ambipolar OFETs have been realized with a variety of material combinations, including polymer/fullerene blends [6], mixtures of soluble oligomers [7] as well as evaporated molecular hetero-layer structures and mixed layers [8].  
Our recent studies in this field have focussed on the combination of hole conducting copper-phthalocyanine (CuPc) with the electron conducting fullerene C60. We have investigated OFETs with various mixing ratios and film preparation conditions and have demonstrated ambipolar inverters with  these blends [9]. Using photoelectron spectroscopy, we have recently determined the occupied electronic levels and their changes upon mixing both materials [10]. In this contribution we will summarize these results and discuss their implications in the context of photovoltaic cells based on a combination of CuPc as electron donor and C60 as electron acceptor, respectively. In particular we will demonstrate that differences in the open-circuit voltages of heterolayer cells and bulk-heterojunction devices can be traced back to the electronic structure of the blends.
3楼2008-04-21 18:54:44
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xiaowenzhi16

铁杆木虫 (正式写手)

★ ★ ★
04120152(金币+3):谢谢,但不全 1-27 23:58
今年来,有机半导体由于其作为一种潜力在电子和光电器件应用中不断增强的的活性材料,引起了人们的极大兴趣。然而,长期以来它们是电子单向传输的典范材料。不同有机材料构成的多层结构,其固有的电子和空穴传输层在空间上的分离特性,是制备有效有机发光二极管的可靠保证。在光伏器件方面,因有机半导体里面激子扩散长度原因,P和N型传导材料必须通过在一单层上混合而到达紧密接触生长出所谓的块体-异质结结构。最近,这种施主-和收住混合物也用于在有机场效应管。
2楼2008-04-21 16:48:05
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04120152

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请版主吧帖子关了,时间太久了
4楼2009-01-27 23:59:50
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