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25¡¢Heterogeneous Catalysis in Organic Chemistry
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ÐÂÊéÒ»±¾£¬Handbook of Heterogeneous Catalysis
Copyright © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. All rights reserved.
Last updated: 14 Mar 2008

http://mrw.interscience.wiley.com/emrw/9783527610044/home/

Reference Work Home  |  Editors & Contributors  |  How to Order  |  Sample Content


Accelerate your chemical reactions with a new and improved resource


With almost 200 expert articles in 8 parts, Handbook of Heterogenous Catalysis provides easily searchable yet comprehensive information.

This new edition takes into account the latest developments in the field , making it the most up-to-date compendium in heterogeneous catalysis.

More than 400 leading experts ¡ª a real "Who's Who" in catalysis ¡ª contributed to this unrivalled masterpiece, covering all aspects of the subject, from the physico-chemical fundamentals to large-scale industrial applications.

With its straightforward presentation, this encyclopedia is an indispensable tool for everybody who applies and researches heterogeneous catalysis.

This title is also available in print. For further information regarding this format please visit www.wiley.com .



Contents:

1 Introduction

1.1 Principles of Heterogeneous Catalysis (James A. Dumesic)

1.2 Development of the Science of Catalysis (Burtron H. Davis)

1.3 Development of Industrial Catalysis (Uwe Dingerdissen)

2 Preparation of Solid Catalysts

2.1 Developing Industrial Catalysis (Ewald Gallei)

2.2 Computer-Aided Strategies for Catalyst Development (Manfred Baerns)

2.3 Bulk Catalysts and Supports

2.3.1 Fused Catalysts (Robert Schlögl)

2.3.2 Skeletal Metal Catalysts (Mark S. Wainwright)

2.3.3 Precipitation and Co-precipitation (Ferdi Sch¨¹th)

2.3.4 Sol-Gel Process (Miron V. Landau)

2.3.5 Hydrothermal Zeolite Synthesis (Pierre A. Jacobs)

2.3.6 Ordered Mesoporous Materials (Freddy Kleitz)

2.3.7 Pillared Clays (Jos¨¦ J. Fripiat)

2.3.8 Metal Organic Frameworks (Ulrich M¨¹ller)

2.3.9 Sulfated Zirconia and Related Materials (Friederieke Jentoft)

2.3.10 Ion Exchange Resins (Bruce C. Gates)

2.3.11 Flame Hydrolysis (Dieter Kerner)

2.3.12 Solid-State Reactions (Bernard Delmon)

2.3.13 Heteropoly Compounds (Makoto Misono)

2.3.14 High-Surface Area Carbides, Nitrides and Phosphides (S. Ted Oyama)

2.3.15 Carbons (Robert Schlögl)

2.4 Supported Catalysts

2.4.1 Deposition Precipitation (John W. Geus)

2.4.2 Impregnation and Ion Exchange (Michel Che)

2.4.3 Solid-State Ion Exchange in Zeolites ( Hellmut G. Karge)

2.4.4 Metal Clusters in Zeolites (Wolfgang M. H. Sachtler)

2.4.5 Anchoring and Grafting of Coordination Metal Complexes onto Oxide Surfaces (Michel Che)

2.4.6 Chemical Vapor Deposition and Related Techniques (Yasuhiro Iwasawa)

2.4.7 Spreading and Wetting (Helmut Knözinger)

2.4.8 Tribochemical Methods (Bernd Kubias)

2.4.9 Immobilization of Molecular Catalysts (Reiner Anwander)

2.4.10 Ship-in-the-Bottle Catalysts (Stefan Ernst)

2.4.11 Supported Liquid Catalysts (Peter Wasserscheid)

2.4.12 Immobilization of Biological Catalysts (Marion B. Ansorge-Schumacher)

2.5 Formation of the Final Catalyst

2.5.1 Reactions during Catalyst Activation (Bernard Delmon)

2.5.2 Catalyst Forming (Ferdi Sch¨¹th)

2.6 Standard Catalysts

2.6.1 Non-Zeolitic Standard Catalysts (Geoffrey C. Bond)

2.6.2 Zeolite Standard Catalysts (Michael Stöcker)

3 Characterization of Solid Catalysts

3.1 Physical Properties

3.1.1 Surface Area and Porosity (Kenneth S. W. Sing)

3.1.2 Particle Size and Dispersion Measurements (Pierre Gallezot)

3.1.3 Structure and Morphology X-Ray Powder Diffraction (Daniel Herein)
3.1.3.2 X-Ray Absorption Spectroscopy (Diek C. Koningsberger)
3.1.3.3 Electron Microscopy and Diffraction (Sbhaya K. Datye)
3.1.3.4 Scanning Probe Techniques (Flemming Besenbacher)
3.1.3.5 Heterogeneous Catalysis and High Electric Fields (Norbert Kruse)
3.1.3.6 Gamma Spectroscopy (J. W. Niemantsverdriet)
3.1.3.7 Solid-State NMR Spectroscopy (Michael Hunger)
3.1.3.8 Vibrational Spectroscopy (Helmut Knözinger)
3.1.3.9 Neutron Scattering (Herv¨¦ Jobic)
3.1.3.10 Morphological Characteristics (Friedrich Schmidt)

3.1.4 Mechanical Properties (Friedrich Schmidt)

3.2 Chemical Properties  

3.2.1 Bulk Chemical Composition (Peter Albers)

3.2.2 Surface Chemical Composition (Edmund Taglauer)

3.2.3 Valence States

3.2.3.1 Photoelectron and Auger Electron Spectroscopy (Giuliano Moretti)
3.2.3.2 UV/Vis and EPR Spectroscopy (Michel Che)
3.2.3.3 Photoluminescence Spectroscopy (Masakazu Anpo)
3.2.3.4 Muon Spin Resonance (Emil Roduner)
3.2.3.5 Temperature-Programmed Reduction and Oxidation (Helmut Knözinger)

3.2.4 Acidity and Basicity
3.2.4.1 Concepts and Analysis of Surface Acidity and Basicity (Hellmut G. Karge)
3.2.4.2 Thermochemical Characterization of Surface Acidity and Basicity (James A. Dumesic)
3.2.4.3 IR Spectroscopy for the Characterization of Surface Acidity and Basicity (Helmut Knözinger)
3.2.4.4 NMR Spectroscopy for the Characterization of Surface Acidity and Basicity (Michael Hunger)

3.2.5 Active Phase-Support Interactions
3.2.5.1 Metal-Support Interactions (Bert M. Weckhuysen)
3.2.5.2 Oxide-Oxide Interactions (Bert M. Weckhuysen)

3.2.6 Carbonaceous Deposits (Peter Albers)

3.3 IUPAC Recommandations

3.3.1 Reporting Physisorption Data for Gas/Solid Systems

3.3.2 Methods and Procedures for Catalyst Characterization (J. Haber, J. H. Block, B. Delmon)

4 Model Systems

4.1 Single-Crystal Surfaces (Gabor A. Somorjai)

4.2 Supported Metal Clusters (Bruce C. Gates)

4.3 Metallic Glasses (Alfons Baiker)

4.4 Bimetallic Model Catalysts (Jos¨¦ A. Rodriguez)

4.5 Ultrathin Oxide Films (Hans-Joachim Freund)

4.6 Oxide Model Systems (Hicham Idriss)

4.7 Microcrystalline Oxides (Adriano Zecchina)

4.8 Oxide Solid Solutions (Frank S. Stone)

5 Elementary Steps and Mechanisms

5.1 Chemisorption

5.1.1 Principles of Chemisorption (Hans-Joachim Freund)

5.1.2 Reactivity Index Relations in Theoretical Heterogeneous Catalysis (Rutger van Santen)

5.2 Microkinetics

5.2.1 Rates of Catalytic Reactions (James A. Dumesic)

5.2.2 Dynamics of Surface Reactions (G. Ertl)

5.2.3 Theoretical Modelling of Catalytic Reactions (Jens K. Nørskov)

5.2.4 Non-linear Dynamics: Oscillatory Kinetics and Spatio-Temporal Pattern Formation (Gerhard Ertl)

5.2.5 Isotopic Labeling and Kinetic Isotope Effects (Frank Bauer)

5.2.6 Transient Catalytic Studies (Kai-Olaf Hinrichsen)

5.3 Factors Influencing Catalytic Action

5.3.1 Substituent Effects (Helmut Knözinger)

5.3.2 Spillover Effects (Frank Rößner)

5.3.3 Ensemble and Ligand Effects in Metal Catalysis (Wolfgang M. H. Sachtler)

5.3.4 Promotors and Poisons (Bruce E. Koel)

5.4 Hydrocarbon Reaction Mechanisms (Bruce C. Gates)

5.5 Computer Simulations

5.5.1 Computer Simulations of Structures and Reactivity (C. Richard A. Catlow)

5.5.2 Molecular Simulation of Adsorption and Diffusion (Doros N. Theodorou)

5.5.3 Computer Simulation of Shape Selectivity Effects (Berend Smit)

6 Makrokinetics and Transport Processes

6.1 Rate Procurement and Kinetic Modelling (Jacob A. Moulijn)

6.2 Diffusion Coefficients in Porous Media (Jörg Kärger)

6.3 Simultaneous Heat and Mass Transfer and Chemical Reaction (Gerhard Emig)

6.4 NMR Tomography (Lynn Gladden)

6.5 Positron Emitters in Catalysis Research (Gert Jonkers)

6.6 Computational Fluid Dynamics Simulation of Catalytic Reactors (Olaf Deutschmann)

7 Activity Loss

7.1 Deactivation and Regeneration (Jacob A. Moulijn)

7.2 Recycling of Spent Catalysts  

7.2.1 Recycling of Spent Catalysts Containing Precious Metals (Christian Hagel¨¹ken)

7.2.2 Recycling of Spent Catalysts Containing Base Metals (Sean Axon)

8 Special Catalytic Systems

8.1 Electrocatalysis

8.1.1 Fundamentals of Electrocatalysis (Katharina Krischer)

8.1.2 Electrochemical Modification of Catalytic Activity (Costas G. Vayenas)

8.1.3 Industrial Electrocatalysis (Sigmar Bräuninger)

8.2 Photocatalysis (M. Anpo)

8.3 Chemical Sensors Based on Catalytic Reactions (Klaus Schierbaum)

8.4 Heterogeneous Catalysis in Non-Conventional Solvents (Roger Gläser)

8.5 Sonocatalysis (Kenneth S. Suslick)

9 Laboratory Testing of Solid Catalysts

9.1 Laboratory Catalytic Reactors: Aspects of Catalyst Testing (Jacob A. Moulijn)

9.2 Ancillary Techniques in Laboratory Units for Catalyst Testing (Jens Weitkamp)

9.3 High-Throughput-Experimentation in Heterogeneous Catalysis (Ferdi Sch¨¹th)

10 Reaction Engineering

10.1 Catalytic Fixed-Bed Reactors (Gerhart Eigenberger)

10.2 Fluidized-Bed Reactors (Joachim Werther)

10.3 Slurry Reactors (Adrian Schumpe)

10.4 Unsteady-State Reactor Operation (Eng. Yurii Matros)

10.5 Short-Contact-Time Reactors (Götz Veser)

10.6 Catalytic Distillation (Domenico Sanfilippo)

10.7 Membrane Reactors (J¨¹rgen Caro)

10.8 Microstructured Catalytic Reactors (Albert Renken)

11 Environmental Catalysis

11.1 The Role of Catalysis in Environmental Protection (Wilhelm Keim)

11.2 Automotive Exhaust Treatment (Egbert Lox)

11.3 Treatment of Flue Gases from Stationary Sources (Pär Gabrielsson)

11.4 Catalytic Dehalogenation (R. F. Howe)

11.5 Removal of Volatile Organic Compounds (James J. Spivey)

11.6 Catalytic Combustion (Pio Forzatti)

11.7 Catalytic Routes to Hydro(chloro)fluorocarbons (Z. Ainbinder)

11.8 Heterogeneous Catalysis in the Troposphere (Valentin M. Parmon)

11.9 Conversion of Biomass on Solid Catalysts (Pierre Gallezot)

11.10 Catalysis in Water Remediation (Klaus-Dieter Vorlop)

12 Inorganic Reactions

12.1 Ammonia Synthesis (Robert Schlögl)

12.2 Ammonia Oxidation (Stephan T. Hatscher)

12.3 HCN Production (Jörg Sauer)

12.4 Claus Process (Eckhard J¨¹ngst)

12.5 Oxidation of Sulfur Dioxide (Fritz Näumann)

12.6 M¨¹ller-Rochow Synthesis (Wilfried Kalchauer)

12.7 Hydrazine Decomposition (Wilhelm Keim)

13 Energy-Related Catalysis

13.1 Perspectives in Oil Refining (Colin Baudouin)

13.2 Hydrotreating (Roel Prins)

13.3 Hydrodemetalation

13.4 Catalytic Reforming (Mark D. Moser, Paula L. Bogdan)

13.5 Fluid Catalytic Cracking (E. Thomas Habib, jr.)

13.6 Hydrocracking and Dewaxing (J. A. Rob van Veen)

13.7 Isomerization (S. T. Sie)

13.8 Alkylation of Isobutane (Jens Weitkamp)

13.9 Oligomerization of Alkenes (Cril T. O'Connor)

13.10 Etherification (Outi Krause)

13.11 Steam Reforming (Jens Rostrup-Nielsen)

13.12 Water Gas Shift (Martin Muhler)

13.13 Methanol Synthesis (John Bogild Hansen)

13.14 Methanol to Hydrocarbons (Steinar Kvisle)

13.15 Fischer-Tropsch Synthesis (Mark E. Dry)

13.16 Gas-to-Liquids (Arend Hoek)

13.17 Oxidative Coupling of Methane (Manfred Baerns)

13.18 Catalysis in Direct Coal Hydrogenation (Matthias W. Haenel)

13.19 Catalysis in Coal and Carbon Gasification (Ljubisa R. Radovic)

13.20 Fuel Cell-Related Catalysis  

13.20.1 Fuel Processors (Ralf Peters)

13.20.2 Fuel Cells (J¨¹rgen Garche)

14 Organic Reactions

14.1 Aromatization of Light Alkanes (Cyril T. O'Connor)

14.2 Ring Opening of Aromatics (Jens Weitkamp)

14.3 Alkylation of Aromatics (David L. Stern)

14.4 Isomerization and Transalkylation of Alkylaromatics (Jeffrey S. Beck)

14.5 Non-Oxidative Activation of Alkanes (Yvonne Traa)

14.6 Dehydrogenation of Alkanes (Karl J. Caspary)

14.7 Dehydrogenation of Ethylbenzene (Martin Muhler)

14.8 Metathesis of Alkenes (J. C. Mol)

14.9 Dehydrogenation of Alcohols: Formaldehyde (Wei-Lin Dai)

14.10 Hydrogenation Reactions

14.10.1 Selective Hydrogenation of Hydrocarbons (Johann Gaube)

14.10.2 Selective Hydrogenation of Functionalized Hydrocarbons (Hans-Ulrich Blaser)

14.10.3 Regioselective Hydrogenations (Peter Claus)

14.10.4 Oleochemical Reactions (Bernhard Gutsche)

14.11 Selective Oxidations

14.11.1 Fundamentals of Hydrocarbon Oxidation (J. Haber)

14.11.2 Oxidative Dehydrogenation of Alkanes (Anders Holmen)

14.11.3 Oxyfunctionalization of Alkanes (Stephan Schunk)

14.11.4 Oxyfunctionalization of Alkyl Aromatics (Frank Rosowski)

14.11.5 Direct Ring Oxidation of Aromatics to Phenols (Elias Klemm)

14.11.6 Heterogeneous Catalysis of Alkene Epoxidation (Mark A. Barteau)

14.11.7 Oxyacetylation: Vinyl Acetate from Ethene (Stephan A. Schunk)

14.11.8 Oxidation of C3 Hydrocarbons

14.11.9 Ammoxidation of Hydrocarbons (Robert C. Grasselli)

14.11.10 Ammoximation (Robert C. Grasselli)

14.11.11 Oxidation of Alcohols (Alfons Baiker)

14.11.12 Phenol Hydroxylation and Related Oxidations (Giuseppe Bellussi)

14.12 Amination Reactions (Alfons Baiker)

14.13 Halogenation Reactions (Ratnasamy)

14.14 Acylation of Aromatics (Herman van Bekkum)

14.15 Elimination and Addition Reactions (Helmut Knözinger)

14.16 Stereoselective Reactions

14.16.1 Catalysis on Chiral Surfaces (Alfons Baiker)

14.16.2 Enantioselective Catalysis on Anchored Chiral Complexes (Hans-Ulrich Blaser)

14.16.3 Diastereoselective Catalysis (Mich¨¨le Besson)

14.17 Miscellaneous Catalytic Systems

14.17.1 Hydroformylation on Solid Catalysts (Vladimir A. Likholobov)

14.17.2 Wacker Chemistry with Solid Catalysts (Pierre A. Jacobs)

14.17.3 Oxidations on Immobilized Molecular Catalysis (Dirk De Vos)

14.17.4 Production of Chemicals from Carbon Dioxide (Paul Ratnasamy)

15 Polymerization Reactions

15.1 Polymerization on Phillips-Type Catalysts (Max P. McDaniel)

15.2 Polymerization on Molecular Catalysts (Gerhard Fink)

16 Reactions on Immobilized Biocatalysts (Udo Kragl)

[ Last edited by zirconia on 2008-4-16 at 18:40 ]
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