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Semiconductor Quantum Dots: Organometallic and Inorganic Synthesis Ò³Êý294 ³ö°æÉçrsc Print ISBN: 978-1-84973-985-6 PDF eISBN: 978-1-78262-835-4 Contents Chapter 1 The Preparation of II¨CVI Semiconductor Nanomaterials 01 1.1 Origins of Organometallic Precursors 01 1.2 Inverse Micelles 02 1.3 Organometallic Routes to CdE (E = S, Se, Te) 03 1.3.1 Alternatives to Metal Alkyls 11 1.3.2 Alternatives to TOPO and Novel Solvents 13 1.4 ZnE (E = S, Se, Te) 15 1.5 HgE (E = S, Se, Te) 18 1.6 Anisotropic Quantum Dots 22 1.6.1 Diffusion Model for Anisotropic Growth 25 1.6.2 Tetrapods 28 1.6.3 Seed Growth of Anisotropic Particles 32 1.7 Alloys 35 1.8 Micro¬éuidic Synthesis 39 References 43 Chapter 2 The Preparation of III¨CV Semiconductor Nanomaterials 53 2.1 Properties and Applications of III¨CV Materials 53 2.2 Group III¨CPhosphides 55 2.2.1 Increasing the Emission Quantum Yield of III¨CV Materials 58 2.2.2 The Growth of Anisotropic Particles 60 2.2.3 Other Phosphorus Precursors 62 2.3 Group III¨CArsenides 64 2.3.1 Non-Coordinating Solvent Route 66 2.4 Group III¨CAntimonides 70 2.5 Group III¨CNitrides 71 References 73 RSC Nanoscience & Nanotechnology No. 33 Semiconductor Quantum Dots: Organometallic and Inorganic Synthesis By Mark Green © Mark Green 2014 Published by the Royal Society of Chemistry, www.rsc.org xiii Downloaded on 24/07/2014 09:57:27. Published on 01 July 2014 on http://pubs.rsc.org | doi:10.1039/9781782628354-FP013 Chapter 3 The Preparation of IV¨CVI Semiconductor Nanomaterials 77 3.1 PbE (E = S, Se, Te) 77 3.2 Other Group IV Chalcogenides 87 References 88 Chapter 4 The Preparation of Other Chalcogenides and Pnictide Nanomaterials 92 4.1 Copper-Based Chalcogenides 92 4.2 Other Chalcogenide-Containing Materials 98 4.3 Other Pnictide-Based Materials 103 References 108 Chapter 5 The Synthesis of Core/Shell Quantum Dots 113 5.1 Early Studies on Core/Shell Materials 113 5.2 Organometallic Routes to Core/Shell Nanoparticles 115 5.3 Type I Materials 116 5.3.1 CdSe/ZnS 116 5.3.2 CdSe/CdS 121 5.3.3 Other Type I Core/Shell Materials Based on Group II Chalcogenides 125 5.4 Type II Materials 133 5.4.1 Inverted Core/Shell Structures 138 5.4.2 Multiple-Shell Structures 140 5.5 Core/Shell Structures Based on III¨CV Materials 146 5.6 Core/Shell Structures Based on IV¨CVI Materials 153 References 157 Chapter 6 Ligand Chemistry 166 6.1 The Functions of Ligands 166 6.2 Phosphine Oxide-Based Ligands 167 6.2.1 Tri-n-Octylphosphine Oxide (TOPO) 167 6.2.2 Tri-n-Octylphosphine (TOP) 169 6.3 Amines 170 6.4 Thiols 173 6.5 Carboxylic Acids 176 6.6 Surfactant Exchange 177 6.6.1 Thiol-Based Surfactant Exchange 179 6.6.2 Phosphine-Based Surfactant Exchange 187 6.6.3 Amine-Based Surfactant Exchange 189 6.6.4 Carboxylic Acid-Based Surfactant Exchange 190 6.6.5 Polymers and Dendrimer-Based Surfactant Exchange 191 xiv Contents Downloaded on 24/07/2014 09:57:27. Published on 01 July 2014 on http://pubs.rsc.org | doi:10.1039/9781782628354-FP013 View Online 6.7 Inorganic Ligands 198 6.8 Encapsulation Driven by Hydrophobic Interactions 198 6.9 Calixarenes and Related Macrocyclic Compounds QQ½ØÍ¼20140805220806.jpg |
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