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Semiconductor Quantum Dots:
Organometallic and Inorganic Synthesis
Ò³Êý294
³ö°æÉçrsc
Print ISBN: 978-1-84973-985-6
PDF eISBN: 978-1-78262-835-4
Contents
Chapter 1 The Preparation of II¨CVI Semiconductor Nanomaterials 01
1.1 Origins of Organometallic Precursors 01
1.2 Inverse Micelles 02
1.3 Organometallic Routes to CdE (E = S, Se, Te) 03
1.3.1 Alternatives to Metal Alkyls 11
1.3.2 Alternatives to TOPO and Novel Solvents 13
1.4 ZnE (E = S, Se, Te) 15
1.5 HgE (E = S, Se, Te) 18
1.6 Anisotropic Quantum Dots 22
1.6.1 Diffusion Model for Anisotropic Growth 25
1.6.2 Tetrapods 28
1.6.3 Seed Growth of Anisotropic Particles 32
1.7 Alloys 35
1.8 MicroŽuidic Synthesis 39
References 43
Chapter 2 The Preparation of III¨CV Semiconductor Nanomaterials 53
2.1 Properties and Applications of III¨CV Materials 53
2.2 Group III¨CPhosphides 55
2.2.1 Increasing the Emission Quantum Yield
of III¨CV Materials 58
2.2.2 The Growth of Anisotropic Particles 60
2.2.3 Other Phosphorus Precursors 62
2.3 Group III¨CArsenides 64
2.3.1 Non-Coordinating Solvent Route 66
2.4 Group III¨CAntimonides 70
2.5 Group III¨CNitrides 71
References 73
RSC Nanoscience & Nanotechnology No. 33
Semiconductor Quantum Dots: Organometallic and Inorganic Synthesis
By Mark Green
© Mark Green 2014
Published by the Royal Society of Chemistry, www.rsc.org
xiii
Downloaded on 24/07/2014 09:57:27.
Published on 01 July 2014 on http://pubs.rsc.org | doi:10.1039/9781782628354-FP013
Chapter 3 The Preparation of IV¨CVI Semiconductor Nanomaterials 77
3.1 PbE (E = S, Se, Te) 77
3.2 Other Group IV Chalcogenides 87
References 88
Chapter 4 The Preparation of Other Chalcogenides and Pnictide
Nanomaterials 92
4.1 Copper-Based Chalcogenides 92
4.2 Other Chalcogenide-Containing Materials 98
4.3 Other Pnictide-Based Materials 103
References 108
Chapter 5 The Synthesis of Core/Shell Quantum Dots 113
5.1 Early Studies on Core/Shell Materials 113
5.2 Organometallic Routes to Core/Shell Nanoparticles 115
5.3 Type I Materials 116
5.3.1 CdSe/ZnS 116
5.3.2 CdSe/CdS 121
5.3.3 Other Type I Core/Shell Materials Based on
Group II Chalcogenides 125
5.4 Type II Materials 133
5.4.1 Inverted Core/Shell Structures 138
5.4.2 Multiple-Shell Structures 140
5.5 Core/Shell Structures Based on III¨CV Materials 146
5.6 Core/Shell Structures Based on IV¨CVI Materials 153
References 157
Chapter 6 Ligand Chemistry 166
6.1 The Functions of Ligands 166
6.2 Phosphine Oxide-Based Ligands 167
6.2.1 Tri-n-Octylphosphine Oxide (TOPO) 167
6.2.2 Tri-n-Octylphosphine (TOP) 169
6.3 Amines 170
6.4 Thiols 173
6.5 Carboxylic Acids 176
6.6 Surfactant Exchange 177
6.6.1 Thiol-Based Surfactant Exchange 179
6.6.2 Phosphine-Based Surfactant Exchange 187
6.6.3 Amine-Based Surfactant Exchange 189
6.6.4 Carboxylic Acid-Based Surfactant Exchange 190
6.6.5 Polymers and Dendrimer-Based Surfactant
Exchange 191
xiv Contents
Downloaded on 24/07/2014 09:57:27.
Published on 01 July 2014 on http://pubs.rsc.org | doi:10.1039/9781782628354-FP013
View Online
6.7 Inorganic Ligands 198
6.8 Encapsulation Driven by Hydrophobic Interactions 198
6.9 Calixarenes and Related Macrocyclic Compounds¡ï¡ï¡ï¡ï¡ï¡ï2014Êé¼®³¬¼¶ÌûÁùÎåÈý¡¶°ëµ¼ÌåÁ¿×ӵ㣺½ðÊôÓлúÓëÎÞ»úºÏ³É¡·2014×îÐÂ
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