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Adv. Mater.最新综述:聚集诱导荧光 唐本忠院士出品
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本综述详实的介绍了聚集诱导荧光的形成机理,结构的多样性(包括碳氢化合物AIE体系,杂原子AIE体系,有机金属AIE体系等),与探究高科技应用(光电子器件,荧光传感器,生物成像,智能材料等)。对聚集诱导荧光进行了全面的归纳总结,对此方面研究有很强的指导意义。 Aggregation-Induced Emission: The Whole Is More Brilliant than the Parts 共51页 引文313篇 Ju Mei, Yuning Hong, Jacky W. Y. Lam, Anjun Qin, Youhong Tang, and Ben Zhong Tang* Dr. J. Mei, Dr. Y. Hong, Dr. J. W. Y. Lam, Prof. B. Z. Tang Department of Chemistry, HKUST Jockey Club Institute for Advanced Study, Division of Life Science, Institute of Molecular Functional Materials and Division of Biomedical Engineering,The Hong Kong University of Science & Technology (HKUST) Clear Water Bay, Kowloon, Hong Kong, China E-mail: tangbenz@ust.hk Dr. Y. Hong, Dr. J. W. Y. Lam, Prof. B. Z. Tang HKUST Shenzhen Institute, Hi-tech Park, Nansha, Shenzhen 518057, China Prof. A. Qin, Prof. B. Z. Tang Guangdong Innovative Research Team, SCUT–HKUST Joint Research Laboratory State Key Laboratory of Luminescent Materials and Devices, South China University of Technology (SCUT), Guangzhou 51640 , China Dr. Y. Tang Centre for NanoScale Science and Technology Centre for Maritime Engineering, Control and Imaging, School of Computer Science, Engineering and Mathematics Flinders University, South Australia 5042 , Australia “ United we stand, divided we fall .”–Aesop. Aggregation-induced emission (AIE) refers to a photophysical phenomenon shown by a group of luminogenic materials that are non-emissive when they are dissolved in good solvents as molecules but become highly luminescent when they are clustered in poor solvents or solid state as aggregates. In this Review we summarize the recent progresses made in the area of AIE research. We conduct mechanistic analyses of the AIE processes, unify the restriction of intramolecular motions (RIM) as the main cause for the AIE effects, and derive RIM-based molecular engineering strategies for the design of new AIE luminogens (AIEgens). Typical examples of the newly developed AIEgens and their high-tech applications as optoelectronic materials, chemical sensors and biomedical probes are presented and discussed. |
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2014-08-03 17:58:42, 7.32 M
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