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[资源] ★★★★★★2014书籍超级帖五九八《金属纳米颗粒催化》2014最新书籍

书名Metal Nanoparticles for Catalysis
Advances and Applications
作者Franklin Tao
University of Notre Dame, USA
Email: franklin.tao.2011@gmail.com
页数284
出版社 RSC PRESS
Print ISBN: 978-1-78262-033-4
PDF eISBN: 978-1-78262-103-4
Chapter 1 Introduction: Synthesis and Catalysis on Metal
Nanoparticles 1
Franklin (Feng) Tao, Luan Nguyen and Shiran Zhang
Chapter 2 Nanocatalysis: Definition and Case Studies 6
Choumini Balasanthiran and James D. Hoefelmeyer
2.1 Introduction 6
2.1.1 Flash Synopsis of the History of Catalysis 7
2.1.2 Reporting Turnover Frequency: the Common
Denominator in Catalysis 8
2.2 Factors Contributing to Structure Sensitivity in
Catalysis 9
2.2.1 Statistical Shape Analysis of Polyhedra
Crystals and Relation to Catalysis 9
2.2.2 Equilibrium Shapes of Nanocrystals 11
2.2.3 Surface Restructuring 12
2.2.4 Mobility of Surface Adsorbates 14
2.2.5 Change in the Electronic Structure of Solids
at the Nanometre Scale 14
2.2.6 Example to Illustrate Anomalous TOF
Behavior: Ethane Hydrogenolysis on
Rhodium 15
2.3 Synthesis and Properties of Well-defined
Nanocrystals 16
2.4 The Dawn of Nanocatalysis and Case Studies 18
2.4.1 CO Oxidation on Au 18
2.4.2 TiO2 Nanocrystals with Reactive Facets 19
2.4.3 Catalysis on Shape-controlled Pt Nanocrystals 21
RSC Catalysis Series No. 17
Metal Nanoparticles for Catalysis: Advances and Applications
Edited by Franklin Tao
r The Royal Society of Chemistry 2014
Published by the Royal Society of Chemistry, www.rsc.org
ix
.
Published on 12 June 2014 on http://pubs.rsc.org | doi:10.1039/9781782621034-FP009
2.4.4 Advanced Templating Methods for
Nanocrystal Synthesis 23
2.4.5 Hybrid Nanocrystal Catalysis 23
2.5 Conclusion 24
References 25
Chapter 3 New Strategies to Fabricate Nanostructured Colloidal and
Supported Metal Nanoparticles and their Efficient
Catalytic Applications 30
Kohsuke Mori and Hiromi Yamashita
3.1 Introduction 30
3.2 New Route for the Preparation of Supported Metal
Nanoparticle Catalysts 31
3.2.1 A Photo-assisted Deposition Method Using
a Single-site Photocatalyst 31
3.2.2 A Microwave-assisted Deposition Method 34
3.2.3 Deposition of Size-controlled Metal
Nanoparticles as Colloidal Precursors 35
3.3 Multifunctional Catalysts Based on Magnetic
Nanoparticles 38
3.3.1 Core–shell Magnetic FePt@Ti-containing
Silica Spherical Nanocatalyst 38
3.3.2 Water-soluble FePt Magnetic NPs Modified
with Cyclodextrin 39
3.3.3 FePd Magnetic NPs Modified with a Chiral
BINAP Ligand 41
3.3.4 Core–shell Nanostructured Catalyst for
One-pot Reactions 42
References 44
Chapter 4 Organometallic Approach for the Synthesis of Noble
Metal Nanoparticles: Towards Application in Colloidal
and Supported Nanocatalysis 47
Solen Kinayyigit and Karine Philippot
4.1 Introduction 47
4.2 Organometallic Synthesis of Noble Metal
Nanoparticles 48
4.3 Nanoparticles for Colloidal Catalysis 49
4.3.1 Hydrogenation Reactions 50
4.3.1.1 Ligand Stabilized Nanoparticles as
Catalysts 50
4.3.1.2 Water-soluble Nanoparticles as
Catalysts 52
x Contents
.
Published on 12 June 2014 on http://pubs.rsc.org | doi:10.1039/9781782621034-FP009
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2014-07-24 20:17:32, 9.33 M

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