全文32页,参考文献286篇。
Heteroatom-doped graphene materials: syntheses, properties and applications
作者为Xuewan Wang,a Gengzhi Sun,a Parimal Routh,a Dong-Hwan Kim,a Wei Huangb and Peng Chen*a
异相原子掺杂可以赋予石墨烯各种新颖或者改善的电磁性质、物理化学性质、光化学性质、光学性质以及结构性质,可以极大地拓展石墨烯的功能以及其在光谱上的潜在应用。对于在这些领域的一些最新研究进展,我们全面而又重点地讨论了异相原子掺杂石墨烯的合成、性质以及新兴的应用,对比了目前合成方法的优势,缺点及其掺杂性质,以期可以为控制性的合成提供帮助。我们也重点阐述了一些由掺杂剂的类型,掺杂能力和轮廓的不同以及共掺杂协同效应等诱导的独特性质,希望可以更好地帮助大家理解掺杂的石墨烯材料。我们也对与之相关的能量储存和转换、传感器以及气体储存等应用机理做了着重描述,旨在于可以推动更为有效的应用。
Heteroatom doping can endow graphene with various new or improved electromagnetic, physicochemical, optical, and structural properties. This greatly extends the arsenal of graphene materials and their potential for a spectrum of applications. Considering the latest developments, we comprehensively and critically discuss the syntheses, properties and emerging applications of the growing family of heteroatom-doped graphene materials. The advantages, disadvantages, and preferential doping features of current synthesis approaches are compared, aiming to provide clues for developing new and controllable synthetic routes. We emphasize the distinct properties resulting from various dopants, different doping levels and configurations, and synergistic effects from co-dopants, hoping to assist a better understanding of doped graphene materials. The mechanisms underlying their advantageous uses for energy storage, energy conversion, sensing, and gas storage are highlighted, aiming to stimulate more competent applications.![Chem. Soc. Rev最新掺杂石墨烯综述:Heteroatom-doped graphene materials]()
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