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树枝状聚合物专题:(3)Dendrimers and Other Dendritic Polymers - Wiley 经典
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树枝状聚合物专题:(3)Dendrimers and Other Dendritic Polymers - Frechet J. 2001 Wiley Dendrimers and other Dendritic Polymers 作者:Jean M. J. Fre′chet and Donald A. Tomalia 版权:© 2001 John Wiley & Sons Ltd 目录: I. INTRODUCTION AND PROGRESS IN THE CONTROL OF MACROMOLECULAR ARCHITECTURE 1 Introduction to the Dendritic State . . . . . . . . . . . . . . . . . . . 3 2 Structural Control of Linear Macromolecules . . . . . . . . . . . . 45 3 Progress in the Branched Architectural State . . . . . . . . . . . . . 67 4 Developments in the Accelerated Convergent Synthesis of Dendrimers . . . 91 5 Formation, Structure and Properties of the Crosslinked State Relative to Precursor Architecture . . . 111 6 Regioselectively-Crosslinked Nanostructures . . . . . . . . . . . . 147 7 Hybridization of Architectural States: Dendritic-linear Copolymer Hybrids . . . . . . 171 8 Statistically Branched Dendritic Polymers . . . . . . . . . . . . . . 197 9 Semi-Controlled Dendritic Structure Synthesis . . . . . . . . . . . 209 II. CHARACTERIZATION OF DENDRITIC POLYMERS 10 Gel Electrophoretic Characterization of Dendritic Polymers . . . 239 11 Characterization of Dendritically Branched Polymers by Small Angle Neutron Scattering (SANS), Small Angle X-Ray Scattering (SAXS), and Transmission Electron Microscopy (TEM) . . . . . 255 12 Atomic Force Microscopy for the Characterization of Dendritic Polymers and Assemblies . . . . . . . . . . . . . . . . . . . . . . . 285 13 Characterization of Dendrimer Structures by Spectroscopic Techniques . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 309 14 Rheology and Solution Properties of Dendrimers . . . . . . . . . 331 III. PROPERTIES AND APPLICATIONS OF DENDRITIC POLYMERS 15 Dendritic and Hyperbranched Glycoconjugates as Biomedical Anti-Adhesion Agents . . . . . . . . . . . . . . . . . . . . . . . . . 361 16 Some Unique Features of Dendrimers Based upon Self-Assembly and Host-Guest Properties . . . . . . . . . . . . . . . . . . . . . . 387 17 Dendritic Polymers: Optical and Photochemical Properties . . . 425 18 Bioapplications of PAMAM Dendrimers . . . . . . . . . . . . . . 441 19 Dendrimer-based Biological Reagents: Preparation and Applications in Diagnostics . . . . . . . . . . . . . . . . . . . . . . 463 20 Dendritic Polymer Applications: Catalysts . . . . . . . . . . . . . 485 21 Optical Effects Manifested by PAMAM Dendrimer Metal Nano-Composites . . . . . . . . . . . . . . . . . . . . . . . . . . . 515 22 Dendrimers in Nanobiological Devices . . . . . . . . . . . . . . . 547 23 Antibodies to PAMAM Dendrimers: Reagents for Immune Detection, Patterning and Assembly of Dendrimers . . . . . . . . 559 IV LABORATORY PREPARATION OF DENDRIMERS AND CONCLUSION 24 Preparation of ‘Fre′chet-type’ Polyether Dendrons and Aliphatic Polyester Dendrimers by Convergent Growth: An Experimental Primer . . . 569 25 Laboratory Synthesis of Poly(amidoamine) (PAMAM) Dendrimers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 587 26 Synthesis and Characterization of Poly(Propylene imine) Dendrimers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 605 27 Laboratory Synthesis and Characterization of Megamers: Core-shell Tecto(dendrimers) . . . . . . . . . . . . . . . . . . . . 617 28 Conclusion/Outlook – Toward Higher Macromolecular Complexity in the Twenty-first Century . . . . . . . . . . . . . . . 631 |
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