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(ÇóÖú):¹ØÓÚKoutecky-Levich ¹«Ê½µÄ¾ßÌå½âÊͼ°ÈçºÎ¼ÆË㣿
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½üÀ´¿´ÎÄÏ×£¬ÆäÖÐÓÐÒ»¶Î¹ØÓÚ±íÕ÷Ñõ»¹Ô´ß»¯¼ÁPt»îÐÔµÄÒ»¶ÎÃèÊö£¬²»´óÀí½â£¬Çë½Ì¸÷λ³æÓÑ£¬ÔÎÄÈçÏÂ: the specific activities (activity per unit area of catalyst surface, which is usually represented by the kinetic current density, jk) of these particles toward the oxygen reduction reaction (ORR) performed in O2-saturated sulfuric acid solution. The values of jk were obtained from the steady-state polarization curves according to the Koutecky-Levich equation£º jk=£¨j*jL£©/(jL-j) (1£© in eq 1.j is the measuring current density at various potentials on the steady -state polarization curve,and jL is the limiting diffusion current density. The surface area of the catalyst particle used to caculate the current densities were obtained from the charge invovlved in the hysdrogen adsorption /desorption current peak in Cyclic Voltammetry. ÉÏÃæÕâ¶Î»°¶Ô¹«Ê½µÄ½âÊÍÍêÈ«ÕýÈ·Âð? ÎÒÏëÎÊ£º¼ÆËãµçÁ÷ÃܶÈʱ£¬ÓõÄÃæ»ýÊÇÐýתԲÅ̵ļ¸ºÎÃæ»ý»¹ÊÇPtµÄµç»¯Ñ§»îÐÔÃæ»ý£¬ÁíÍ⣬¹«Ê½Öеļ«ÏÞµçÁ÷ÃܶÈÊÇͨ¹ý¼ÆËãµÃ³öÀ´µÄÄØ?»¹ÊÇͨ¹ýÎÈ̬¼«»¯ÇúÏß¶Á³öÀ´µÄ? Èç¹ûÊǶÁ³öÀ´µÄ,²âÊÔORRʱ£¬À©É¢µÄÄǶο´ÆðÀ´ÊÇÆ½µÄ£¬µ«ÊÇÉÏÃæµÄÊýÖµ»¹ÊÇÓÐһЩ²î±ð£¬Ö÷ÒªÊÇСÊýµãºóµÚÈýËÄ룬ËùÒÔÏëÇë½Ìһϴó¼Ò£¬Õâ¸ö¼«ÏÞµçÁ÷Ôõô¶Á°¡£¿ |
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xiusi
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happyboy2008(½ð±Ò+1,VIP+0):·Ç³£¸Ðл£¬Ï£ÍûÄܹ»ºÍÄã½øÒ»²½½»Á÷£¡
happyboy2008(½ð±Ò+1,VIP+0):·Ç³£¸Ðл£¬Ï£ÍûÄܹ»ºÍÄã½øÒ»²½½»Á÷£¡
| Yes. In the case of specific activity, the current density is after normalization by electrochemical surface area. In your picture, the diffusion limit range should be on the left side. |
7Â¥2008-03-20 11:06:33
zhouzhimin2007
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happyboy2008(½ð±Ò+2,VIP+0):·Ç³£¸Ðл£¬²ÎÓëÌÖÂÛ£¡
happyboy2008(½ð±Ò+2,VIP+0):·Ç³£¸Ðл£¬²ÎÓëÌÖÂÛ£¡
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ÎÒ×òÌì°ïÄã·¢ÁËemailÈ¥ÎÊ×÷Õߣ¬»¹Ã»¸øÎһظ´µÄ ¾Ý˵ÔÚµç¶ÆµÄʱºòÓÉÓÚÕæÊµÃæ»ýÈÝÒױ仯£¬ËùÒÔ»¹ÊÇÓñí¹ÛÃæ»ýÀ´Ìæ´ú µ«ÊÇȷʵҲÓÐÕæÊµµçÁ÷ÃܶÈÕâÖÖ˵·¨ |
3Â¥2008-03-19 08:44:31
xiusi
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happyboy2008(½ð±Ò+1,VIP+0):Thanks!
happyboy2008(½ð±Ò+1,VIP+0):Thanks!
| J is the current density normalized by electrochemical surface area |
4Â¥2008-03-19 09:45:53
xiusi
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happyboy2008(½ð±Ò+1,VIP+0):·Ç³£¸Ðл£¡
happyboy2008(½ð±Ò+1,VIP+0):·Ç³£¸Ðл£¡
| That limitation current is OK, roughly is fine. For the Levich plot, you need the value for certain potential. |
5Â¥2008-03-19 09:46:46














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