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[资源] Phys. Chem. Chem. Phys.热点综述:当宏观遇到微观

This article is part of themed collection: PCCP’s 15th anniversary
Where macro meets micro 共13页 引文73篇 请小伙伴们下载后给个好评!
R. Stephen Berry*a and Boris M. Smirnov b
a The University of Chicago, 929 East 57th Street, Chicago, Illinois, USA.
E-mail: berry@uchicago.edu; Tel: +1 773 702 7021
b Joint Institute for High Temperatures, RAN 13/19, Moscow 125412, Russia
DOI: 10.1039/c3cp54550d
Reconciling or somehow linking the macroscopic and microscopic approaches to chemical and physical processes has been a challenge unaddressed for many years. One approach, presented here, treats the issue by examining individual phenomena well described by a macro approach that fails when applied to small systems. The key to the approach is determining the approximate system size below which the breakdown of the macro description is observable. The most developed example is the failure of the Gibbs phase rule for sufficiently small atomic clusters. Other examples, such as the onset, at sufficient size, of the insulator-to-metal transition, are discussed, as are some still more challenging phenomena.Phys. Chem. Chem. Phys.热点综述:当宏观遇到微观
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