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happy308

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[交流] over-screening charge effect和ion confinement应该怎么解释？

Extensive work was done to understand the electrode electrolyte interfaces using various simulation techniques, and it is now recognized that the ions adopt a multilayered structure at the ionic liquid/graphite (planar) electrode interface. Such behavior is described as the “over-screening charge effect":because of electrostatic interactions between ions in IL, the charge carried out by the first layer of ions adsorbed at the carbon surface exceeds the one present at the carbon surface.
recent discoveries of the capacitance increase in carbon pores less than 1 nm have refocused the research efforts toward the understanding of the ion confinement in nanopores for explaining the capacitance increase when the electrolyte ion size matches the carbon pore size

最近看超电大牛Y. Gogotsi和P. Simon关于碳材料应用于超电的综述Capacitive Energy Storage in Nanostructured CarbonElectrolyte Systems，碰到题目中这两个名词，网上没有找到满意的解答，不知道应该如何理解才是正确？

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